Record Display for the EPA National Library Catalog

RECORD NUMBER: 3 OF 3

OLS Field Name OLS Field Data
Main Title Multinuclear NMR Spin Labeling Investigation of the Solution Structure of the Base Stacked Mn(+2) -AMP Complex.
Author Levy, George C. ; Dechter, James J. ;
CORP Author Florida State Univ., Tallahassee. Dept. of Chemistry.;Health Effects Research Lab., Research Triangle Park, NC.
Year Published 1979
Report Number EPA-R-804916; EPA-600/J-80-379;
Stock Number PB82-155284
Additional Subjects Isotopic labeling ; Nuclear magnetic resonance ; Molecular structure ; Nitrogen organic compounds ; Reprints ; Adenine/ribofuranosyl ; Nitrogen 15 ; Carbon 13 ; Phosphorus 31
Holdings
Library Call Number Additional Info Location Last
Modified
Checkout
Status
NTIS  PB82-155284 Most EPA libraries have a fiche copy filed under the call number shown. Check with individual libraries about paper copy. 06/23/1988
Collation 8p
Abstract
(15)N, (13)C, and (31)P electron-nuclear relaxation times are used to determine the solution structure of the base stacked Mn(+2) -AMP complex. The nitrogen-Mn(+2) distances that are determined indicate a direct inner-sphere coordination of Mn(+2) at N(1), N(7), and the amino NH2 positions. The phosphorus-Mn(+2) distance also indicates direct coordination and this second site may explain the anomalously short Mn(+2) -C(8) distance that is found. A structure is proposed consistent with the measured distances. Comparison of Mn(+2) -carbon distances with those in the literature is made.