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RECORD NUMBER: 4 OF 12

OLS Field Name OLS Field Data
Main Title Field Disposal of Methyl Parathion Using Acidified Powered Zinc.
Author Butler, Larry C. ; Staiff, Donald C. ; Sovocool, G. Wayne ; Davis, James E. ;
CORP Author Health Effects Research Lab., Wenatchee, WA. Wenatchee Pesticides Research Branch.
Year Published 1981
Report Number EPA-600/J-80-012;
Stock Number PB82-127945
Additional Subjects Pesticides ; Zinc ; Soils ; Phosphorus organic compounds ; Molecular structure ; Mass spectroscopy ; Gas chromatography ; Sampling ; Concentration(Composition) ; Solid waste disposal ; Chemical reactions ; Reprints ; Methyl parathion ; Land disposal
Holdings
Library Call Number Additional Info Location Last
Modified
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Status
NTIS  PB82-127945 Most EPA libraries have a fiche copy filed under the call number shown. Check with individual libraries about paper copy. NTIS 06/23/1988
Collation 12p
Abstract
The degradation of methyl parathion in soil with various amounts of acidified powdered zinc under field conditions was studied. Treatment was progressively more effective with increasing amounts of zinc. Disappearance of parent compound was followed for 2 1/2 years. The expected conversion product aminomethyl parathion and its N-methyl derivative were formed. In addition, N,N-dimethylamino, and the azo and azoxy condensation products were characterized by high resolution mass spectrometry. Aminomethyl parathion was shown to be identical to an authentic standard. The other specific positional isomers were considered likely, but were not proven by mass spectrometry. Structure elucidation was made with high resolution mass spectrometry, using the direct insertion probe, and with gas chromatography/low resolution mass spectrometry.