Record Display for the EPA National Library Catalog

RECORD NUMBER: 163 OF 285

Main Title Modified Langmuir Equation for Predicting Sorption of Methylacridinium Ion in Soils and Sediments.
Author Brown, D. S. ; Combs, G. ;
CORP Author Environmental Research Lab., Athens, GA.
Year Published 1985
Report Number EPA/600/J-85/058;
Stock Number PB85-219715
Additional Subjects Soil analysis ; Sediments ; Sorption ; Mathematical models ; Environmental surveys ; Ions ; Cations ; Cation exchanging ; Ion exchanging ; Chemical properties ; Calibrating ; Electrolytes ; Reprints ; Acridinium/methyl ; Langmuir equations ; Numerical solution
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NTIS  PB85-219715 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 8p
Abstract
An empirical model for predicting sorption isotherms of organic cations was tested using a set of 10 soils and sediments. The model is based on a competitive Langmuir equation with modifications for grouping the various competing ion species and for normalizing over a broad range of sediment properties. Normalization is accomplished by substituting cation exchange capacities (CECs) determined with NH4(+1) for the Langmuir capacity term. Natural exchange ions are grouped and treated as a single competing species for simplicity. A single calibration enables estimation of sorption isotherms for other sediments for which estimates of CECs and competing electrolyte concentrations are known.