Record Display for the EPA National Library Catalog

RECORD NUMBER: 40 OF 50

Main Title Pressure-Broadening Effects on Infrared Peak Intensities of Hydrocarbons.
Author Altshulle, A. P. ; Wartbur, A. F. ;
CORP Author Robert A. Taft Sanitary Engineering Center, Cincinnati, Ohio.
Year Published 1957
Stock Number PB-215 017
Additional Subjects ( Hydrocarbons ; Infrared spectra) ; ( Gas analysis ; Hydrocarbons) ; Line broadening
Holdings
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Status
NTIS  PB-215 017 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 15p
Abstract
The pressure-broadening effects of one atmosphere of air or of carbon dioxide on various infrared bonds of hydrocarbons have been measured and compared with the intensity data obtained without pressure-broadening. Measurements have been made on the following hydrocarbons at partial pressures between 0.5 and 20 millimeters and at the following wavelengths: ethylene, 10.52 microns; acetylene, 3.1, 7.4 and 13.7 microns; propylene, 10.95 microns; butene-1, 10.85 microns; trans-2-butene, 10.375 microns; and benzene, 9.50 microns. The variation of optical absorbance at several of the infrared absorption maxima of ethylene and acetylene have been investigated using varying partial pressures of air or carbon dioxide at fixed partial pressures of the two hydrocarbons. (Author)