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RECORD NUMBER: 46 OF 73

Main Title Rate Constants for Some Oxidations of S(IV) by Radicals in Aqueous Solutions.
Author Huie, R. E. ; Neta, P. ;
CORP Author National Bureau of Standards (NML), Gaithersburg, MD. Chemical Kinetics Div.;Environmental Protection Agency, Research Triangle Park, NC. Atmospheric Sciences Research Lab.
Year Published 1987
Report Number EPA/600/J-87/324;
Stock Number PB88-202122
Additional Subjects Sulfite ; Oxidation ; Water ; Free radicals ; Acidification ; Experimentation ; Rates(Per time) ; Constants ; Maritine ; Pollution ; Reprints ; Acid rain ; Atmospheric chemistry
Holdings
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Status
NTIS  PB88-202122 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 7p
Abstract
Rate constants were measured for several radical reactions important in the autoxidation of Sulfite(IV) in atmospheric droplets. In some cases, the rate constants are significantly different than those used previously in atmospheric models. The results suggest that secondary radical-radical reactions may be of considerable importance in the mechanism of sulfite autoxidation in the atmosphere. (Copyright (c) Pergamon Journals Ltd., 1987.)