Record Display for the EPA National Library Catalog
RECORD NUMBER: 280 OF 616| Main Title | Electron-Capture Gas Chromatographic Determination of 2-sec-Butyl-4,6-dinitrophenol (DNBP) Residues in Feed, Tissue and Excreta. | |||||||||||
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| Author | Edgerton, Thomas R. ; Moseman., Robert F. ; | |||||||||||
| CORP Author | Health Effects Research Lab., Research Triangle Park, N.C. Environmental Toxicology Div. | |||||||||||
| Year Published | 1977 | |||||||||||
| Report Number | EPA/600/J-78/024; | |||||||||||
| Stock Number | PB-284 754 | |||||||||||
| Additional Subjects | Pesticides ; Herbicides ; Rats ; Laboratory animals ; Tissues(Biology) ; Gas chromatography ; Residues ; Chemical analysis ; Nitrogen organic compounds ; Excretion ; Methodology ; Hydrolysis ; Tables(Data) ; Urine ; Liver ; Blood ; Brain ; Experimental data ; Reprints ; Pesticide residues ; DNBP herbicide ; Phenol/butyl-dinitro ; Adipose tissue | |||||||||||
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| Collation | 6p | |||||||||||
| Abstract | Gas chromatographic methods for determining the herbicide DNBP (2-sec-butyl-4,6-dinitrophenol) in feed, food, urine, feces, and tissues are presented. After extraction the sample was reacted with diazomethane to produce the methyl ether of DNBP prior to analysis by electron-capture gas chromatography. An acid alumina column cleanup was developed to remove interferences from the sample extracts. Average recoveries of greater than 85% were obtained from tissues, excreta, and feed fortified with known amounts of DNBP. Because of apparent binding or salt formation, methodology for freshly fortified and aged feed are also presented. Residue levels of DNBP from rats fed at two feeding levels are also presented. |