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RECORD NUMBER: 22 OF 29

Main Title Photoproduction of Hydrated Electrons from Natural Organic Solutes in Aquatic Environments.
Author Zepp, R. G. ; Braun, A. M. ; Hoigne, J. ; Leenheer, J. A. ;
CORP Author Environmental Research Lab., Athens, GA. ;Ecole Polytechnique Federale de Lausanne (Switzerland). Inst. de Chimie Physique. ;Eidgenoessische Anstalt fuer Wasserversorgung, Abwasserreinigung und Gewaesserschultz, Duebendorf (Switzerland). ;Geological Survey, Lakewood, CO.
Year Published 1987
Report Number EPA/600/J-87/102;
Stock Number PB88-139621
Additional Subjects Protolysis ; Organic materials ; Irradiation ; Stream pollution ; Chemical lasers ; Soils ; Adsorption ; Electrons ; Chlorine organic compounds ; Ethanols ; Chlorides ; Solutes ; Ions ; Suwannee River ; Georgia ; Greifensee Lake ; Switzerland ; Reprints ;
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NTIS  PB88-139621 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 8p
Abstract
Laser flash photolysis was used to investigate the transients formed on absorption of 355-nm light by dissolved organic matter (DOM) from natural water bodies and from soil. Absorption spectra and quenching studies of the transients provided confirming evidence that hydrated electrons were formed by all of the DOM that were studied. The DOM from the Suwannee River in Georgia and from the Greifensee, a Swiss lake, exhibited great variability in light-absorbing properties. Despite the high variability in absorption coefficients, the primary quantum yields for electron ejection from the Greifensee and Suwanee DOM fell in a narrow range (0.005-0.008). (Copyright (c) 1987 by the American Chemical Society and reprinted by permission of the copyright owner.)