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RECORD NUMBER: 7 OF 7

Main Title Thermospray Ionization with Repeller-Induced Collisionally Activated Dissociation of Dyes.
Author Yinon, J. ; Jones, T. L. ; Betowski., L. D. ;
CORP Author Environmental Monitoring Systems Lab., Las Vegas, NV. ;Weizmann Inst. of Science, Rehovoth (Israel).
Publisher c1990
Year Published 1990
Report Number EPA/600/J-90/222;
Stock Number PB91-117168
Additional Subjects Azo dyes ; Mass spectra ; Dissociation ; Dyes ; Molecular structure ; Mass spectroscopy ; Reprints ; Thermospray ionization ; Molecule collisions ; Ion-molecule collisions
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Status
NTIS  PB91-117168 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 8p
Abstract
Thermospray ionization with repeller-induced collisionally activated dissociation (repeller-CAD) has been used to acquire mass spectra of a series of dyes. These were obtained by applying a voltage of 400 V on the wire repeller. The mass spectra contained a large number of fragment ions which were useful for structural elucidation. Some of these fragment ions were found to be similar to those obtained by thermospray tandem mass spectrometry with CAD and some of them were similar to those obtained by electron ionization using a particle beam liquid chromatrography/mass spectrometry interface. The results indicate that more than one mechanism is involved in the fragmentation process. (Copyright (c) John Wiley and Sons Limited, 1990.)