Record Display for the EPA National Library Catalog
RECORD NUMBER: 14 OF 16| Main Title | Spectroscopic Characterization of Some Chlorinated Tricyclic Hydrocarbons of the C10 Series: Chlordanes, Chlordenes and Nonachlors. | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Author | Wilson, Nancy K. ; Sovocool., G. Wayne ; | |||||||||||
| CORP Author | Health Effects Research Lab., Research Triangle Park, N.C. Environmental Toxicology Div. | |||||||||||
| Year Published | 1977 | |||||||||||
| Report Number | EPA/600/J-77/098; | |||||||||||
| Stock Number | PB-278 615 | |||||||||||
| Additional Subjects | Pesticides ; Chlordan ; Spectrochemical analysis ; Chlorine organic compounds ; Molecular structure ; Nuclear magnetic resonance ; Mass spectroscopy ; Infrared spectroscopy ; Ultraviolet spectroscopy ; Reprints ; Methanoindene/octachloro-hexahydro ; Compound K ; Chlordene ; Nonachlor ; Methanoindan/nonachloro-tetrahydro | |||||||||||
| Holdings |
|
|||||||||||
| Collation | 8p | |||||||||||
| Abstract | Carbon-13 and proton nuclear magnetic resonance (n.m.r.) spectra of ten chlorinated hydrocarbons, which are components of technical chlordane and one chlordane metabolite, were examined. For chlordene, dichlorochlordene, cis- and trans-nonachlor, and cis- and trans-chlordane, whose chemical structures are well-established, the relationships between the n.m.r. parameters and these structures were investigated. The results allow confirmation of proposed structures for alpha-, beta- and gamma-chlordene. A structure, corresponding to 2,4,5,5,6,7,8,8-octachloro-2,3,3a,4,5,7a-hexahydro-1,4-methano-1-H-indene, is proposed for another chlordane component, previously known only as Compound K. (Copyright (c) Heyden & Son Ltd., 1977.) |