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RECORD NUMBER: 3 OF 3

Main Title Photolysis Rates of (2,4,5-Trichlorophenoxy)Acetic Acid and 4-Amino-3,5,6-Trichloropicolinic Acid in Natural Waters.
Author Skurlatov, Y. I. ; Zepp, R. G. ; Baughman, G. L. ;
CORP Author Environmental Research Lab., Athens, GA. ;Akademiya Nauk SSSR, Moscow. Inst. Khimicheskoi Fiziki.
Year Published 1983
Report Number EPA-600/J-83-143;
Stock Number PB84-142488
Additional Subjects Water pollution ; Herbicides ; Photochemical reactions ; Reaction kinetics ; Photolysis ; Solutions ; Sunlight ; Chlorine organic compounds ; Pesticides ; Reprints ; T 2-4-5 herbicide ; Picloram ; Picolinic acid/amino-trichloro ; Acetic acid/trichlorophenoxy
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NTIS  PB84-142488 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 10p
Abstract
Photoreactions of (2,45-trichlorophenoxy) acetic acid (2,4,5-T) and 4-amino-3,5,6-trichloropicolinic acid (picloram) were studied in distilled water, natural water samples, fulvic acid solutions, and solutions containing iron (III) and/or hydrogen peroxide to determine the effects of dissolved natural substances on the photolysis rates of these herbicides. Most of the experiments were conducted with sunlight as the light source and with dilute solutions of 3,4-dichloroaniline (DCA) as an outdoor actinometer. Preliminary studies indicated that photocatalytic processes involving iron species and peroxides may contribute to the sunlight-induced reaction of 2,4,5-T in acidic, weakly absorbing natural waters.