| Main Title |
Production of Organic Nitrates from Hydroxyl and Nitrate Radical Reaction with Propylene. |
| Author |
Shepson, P. B. ;
Edney, E. O. ;
Kleindienst, T. E. ;
Pittman, J. H. ;
Namie, G. R. ;
|
| CORP Author |
Northrop Services, Inc./Environmental Sciences, Research Triangle Park, NC.;Environmental Protection Agency, Research Triangle Park, NC. Atmospheric Sciences Research Lab. |
| Year Published |
1985 |
| Report Number |
EPA-68-02-4033; EPA/600/J-85/519; |
| Stock Number |
PB88-159694 |
| Additional Subjects |
Nitrates ;
Reprints ;
Propylene ;
Hydroxyl ;
Gas phase production rates
|
| Holdings |
| Library |
Call Number |
Additional Info |
Location |
Last
Modified |
Checkout
Status |
| NTIS |
PB88-159694 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
| Collation |
8p |
| Abstract |
Measurements of the gas-phase production rates of alpha-nitratoacetone, propylene glycol dinitrate, 2-hydroxy propyl nitrate, and 2-nitrato propyl alcohol (2-NPA) in a C3H6/N2O5/air dark reaction and a C3H6/NOX/air irradiation are reported. The probable operative reaction mechanisms are discussed and the branching ratios for peroxy radical reaction with no via RO2 + NO -> RONO2 versus RO2 + NO -> RO +NO2 are estimated for CH3CH(OO)CH2OH and CH3CH(OH)CH2OO radicals. |
