Record Display for the EPA National Library Catalog

RECORD NUMBER: 8 OF 38

Main Title Algal-Induced Decay and Formation of Hydrogen Peroxide in Water: Its Possible Role in Oxidation of Anilines by Algae.
Author Zepp, R. G. ; Skurlatov, Y. I. ; Pierce, J. T. ;
CORP Author Environmental Research Lab., Athens, GA. ;Akademiya Nauk SSSR, Moscow. Inst. Khimicheskoi Fiziki.
Year Published 1986
Report Number EPA/600/D-86/227;
Stock Number PB87-105532
Additional Subjects Hydrogen perioxide ; Deterioration ; Algae ; Streams ; Water pollution ; Photoproduction ; Exposure ; Oxidation ; Anilines ; Biomass ; Reaction kinetics ; Oxidants ;
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NTIS  PB87-105532 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 14p
Abstract
Studies of the rates of decomposition and photoproduction of hydrogen peroxide (H2O2) by several green and blue-green algae in water are reported. Results suggest that algae have an important influence on the environmental concentration of H2O2, a widely distributed oxidant in natural waters. The algal-catalyzed decomposition of H2O2 in the dark was found to be second-order overall, first-order with respect to H2O2, and first-order with respect to algal biomass. Exposure of algal suspensions to sunlight resulted in a build up of H2O2, indicating that algae can photoproduce as well as decompose the oxidant. Kinetic results for the algal-induced photooxidation of substituted anilines are presented and a mechanism involving the intermediacy of H2O2 is discussed.