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RECORD NUMBER: 4 OF 9

Main Title Reactions of ozone with organics in aqueous solutions /
Author Kuo, C. H.
CORP Author Mississippi State Univ., Mississippi State. Dept. of Chemical Engineering.;Environmental Protection Agency, Research Triangle Park, NC. Atmospheric Sciences Research Lab.
Publisher U.S. Environmental Protection Agency, Office of Research and Development, Atmospheric Sciences Research Laboratory,
Year Published 1985
Report Number PB85-191179; EPA/600/3-85/031
Stock Number PB85-191179
OCLC Number 663579261
Subjects Ozonization ; Aromatic amines ; Polycyclic aromatic hydrocarbons
Additional Subjects Ozonization ; Reaction kinetics ; Air water interactions ; Oxidation ; Aromatic compounds ; Air pollution ; Photochemical reactions ; pH ; Experimental design ; Solutions ; Mass flow ; Water pollution ; Chemical reaction mechanisms
Internet Access
Description Access URL
https://nepis.epa.gov/Exe/ZyPDF.cgi?Dockey=9100M029.PDF
Holdings
Library Call Number Additional Info Location Last
Modified
Checkout
Status
EJBD  EPA 600-3-85-031 c.1 Headquarters Library/Washington,DC 03/05/2013
ELBD ARCHIVE EPA 600-3-85-031 Received from HQ AWBERC Library/Cincinnati,OH 10/04/2023
NTIS  PB85-191179 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation xi, 54 p. : ill. ; 28 cm.
Abstract
Rates of ozonation of some organic pollutants in the aqueous phase were studied. Experiments were conducted in distilled water with pH varying between 2 and 7; the solution temperature ranged from 5C to 35C. Aromatic amines were very reactive with ozone and the reactions were second order. The rate of the naphthylamine/ozone reaction increased with temperature. The aniline/ozone reaction was faster, but was unaffected by temperature changes. The toluene/ozone reaction exhibited a moderate rate. The order of the reaction changed with pH changes. PAHs including naphthalene, anthracene, and phenanthrene reacted with ozone according to second order kinetics. The reaction between ozone and anthracene was the fastest of all systems studied and the reaction rate was nearly independent of acidity.
Notes
Includes bibliographical references (p. 52-54). Cover title. "April 1985." "EPA/600/3-85/031." "PB85-191179." "Cooperative Agreement CR808799." "EPA Project Officer, H. M. Barnes."