Record Display for the EPA National Library Catalog

RECORD NUMBER: 9 OF 13

Main Title Photochemical oxidation of kraft air pollutants /
Author Bentley., Michael D.
Other Authors
Author Title of a Work
Bentley, Michael.
Dodge, Marcia C.
CORP Author Maine Univ., Orono.;National Environmental Research Center, Research Triangle Park, N.C. Chemical and Physics Lab.
Publisher Chemistry and Physics Laboratory, National Environmental Research Center,
Year Published 1975
Report Number EPA-650/3-75-005; EPA-600/3-75-005; EP-800209; EPA-ROAP-26AAD-14
Stock Number PB243599
OCLC Number 52568206
Subjects Photochemical oxidants ; Atmospheric chemistry ; Oxidation
Additional Subjects Photochemical reactions ; Organic sulfides ; Air pollution ; Pulp mills ; Sulfate pulping ; Oxidation reactions ; Methane thiols ; Disulfide/dimethyl ; Thiols
Internet Access
Description Access URL
https://nepis.epa.gov/Exe/ZyPDF.cgi?Dockey=2000FM8Y.PDF
Holdings
Library Call Number Additional Info Location Last
Modified		 Checkout
Status
EJBD  EPA 650-3-75-005 Headquarters Library/Washington,DC 10/02/2014
EKBD  EPA-650/3-75-005 Research Triangle Park Library/RTP, NC 01/03/2017
ELBD ARCHIVE EPA-650-3-75-005 Received from HQ AWBERC Library/Cincinnati,OH 10/04/2023
ELBD  EPA 650-3-75-005 AWBERC Library/Cincinnati,OH 03/01/2021
NTIS  PB-243 599 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation v, 11 leaves : illustrations ; 28 cm.
Abstract
The photolysis of methyl mercaptan, dimethyldisulfide, and methylmethanethiolsulfonate were studied. The photolysis of methyl mercaptan in air was shown to yield dimethyl disulfide, methanesulfonic acid, ethyl mercaptan, methanol, formic acid, methane, sulfur trioxide, and sulfur dioxide in addition to other presently unidentified compounds. The photolysis of dimethyldisulfide in air was shown to yield methanesulfonic acid, methylmethanethiolsulfonate, methanesulfinic acid, methyl formate, sulfur, sulfur dioxide, sulfur trioxide, and other presently unidentified compounds. The photolysis of methylmethanethiolsulfonate in tetrahydrofuran resulted in formation of methane, methyl mercaptan, dimethyl sulfide, dimethyldisulfide, methanesulfinic acid, methanesulfonic acid, and sulfur dioxide. N-isopropyl-S-benzylsulfenamide was found to undergo an unusual thermal elimination to form N-isopropylbenzaqlimine. Lithium amides were found to form sulfenamides upon reaction with disulfide.
Notes
"EPA Project Officer: Dr. Marcia Dodge." "Prepared for U.S. Environmental Protection Agency, Office of Research and Development." "EPA-650/3-75-005 " "May 1975." "Grant No. 800209; Project No. 26AAD-14; Program Element No. 1A1008." PB 243 599--NTIS. Includes bibliographical references (page 11).