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Main Title N-Octanol/Water Partition Coefficients by Reverse Phase Liquid Chromatography/Mass Spectrometry for Eight Tetrachlorinated Planar Molecules.
Author Burkhard, L. P. ; Kuehl, D. W. ;
CORP Author Wisconsin Univ.-Superior. Center for Lake Superior Environmental Studies.;Environmental Research Lab.-Duluth, MN.
Year Published 1986
Report Number EPA/600/J-86/103;
Stock Number PB86-215563
Additional Subjects Solubility ; Chemical analysis ; Mass spectroscopy ; Carbazales ; Chlorine organic compounds ; Reprints ; Partition coefficients ; Liquid chromatography ; Dibenzofurans ; Dibenzodioxins ; Biphenylenes
Library Call Number Additional Info Location Last
NTIS  PB86-215563 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 7p
In understanding and modeling the toxicological and pharmacokinetic properties of organic chemicals, physical-chemical properties such as aqueous solubilities, vapor pressures, and n-octanol/water partition coefficients are required. Currently, the octanol/water partition coefficients (K sub ow's) are limited for chlorinated planar molecules, e.g., dibenzo-p-dioxins, dibenzofurans, biphenylenes, and carbazoles. In the paper, log K sub ow's determined using a reverse phase liquid chromatography/mass spectrometry technique are reported for eight tetrachlorinated planar molecules. In addition, the authors report a reevaluation of log K sub ow's for fifteen polychlorinated dibenzofurans and dibenzo-p-dioxins previously reported by Sarna et al. The reevaluation was performed by using experimental rather than estimated log K sub ow's in the correlative relationship.