Record Display for the EPA National Library Catalog
RECORD NUMBER: 24 OF 27
|OLS Field Name||OLS Field Data|
|Main Title||Role of gas-phase C12 in the formation of PCDD/PCDF in municipal and hazardous waste combustion [microfiche] /|
|Author||Bruce, K. R. ; Beach, L. O. ; Gullett, B. K.|
|CORP Author||Acurex Corp., Research Triangle Park, NC.;Environmental Protection Agency, Research Triangle Park, NC. Air and Energy Engineering Research Lab.|
|Publisher||U.S. Environmental Protection Agency, Office of Research and Development, Air and Energy Engineering Research Laboratory,|
|Report Number||EPA-68-02-4701; EPA/600/D-90/023|
|Subjects||Mass spectrometry--Mathematical models. ; Gases.|
|Additional Subjects||Hazardous materials ; Incinerators ; Pollution control ; Chlorine ; Municipalities ; Toxicity ; Fly ash ; Catalysts ; Decomposition reactions ; Temperature ; Concentration(Composition) ; Gases ; Reprints|
The paper proposes a scheme for controlling the formation of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) during incineration using sorbent materials to remove the source of chlorine at high temperature. Results of previous experiments investigating the formation of PCDD/PCDF through low temperature (300C), fly-ash-catalyzed reactions are demonstrated to have occurred through intermediate formation of gas-phase Cl2 by decomposition of the added catalyst CuCl2. The dependence of PCDD/PCDF formation rates on Cl2 concentration is shown and the implications of the Deacon process on these rates is discussed.
"EPA 600/D-90/023." Microfiche.