Grantee Research Project Results
Publications Details for Grant Number R826236
RO2 and HOx Radicals in Urban and Rural Air: Measurements of OH and RO2 Formation From Ozone-Alkene Reactions, and the Rate Coefficients of the Reactions of High Molecular Weight RO2 Radicals with HO2
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Reference Type | Reference Title | Journal | Author | Citation | Progress Report Year | Document Sources |
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Journal Article | Kinetics of HO2 + HO2--> H2O2 + O2:implications for stratospheric H2O2. | GEOPHYSICAL RESEARCH LETTERS | Christensen LE, Okumura M, Sander SP, Salawitch RJ, Toon GC, Sen B, Blavier J-F, Jucks KW | Christensen LE, Okumura M, Sander SP, Salawitch RJ, Toon GC, Sen B, Blavier J-F, Jucks KW. Kinetics of HO2 + HO2--> H2O2 + O2:implications for stratospheric H2O2. Geophysical Research Letters 2002;29(9):1299 (4 pp.). |
R826236 (Final) |
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Journal Article | Measurements of the rate constant of HO2 + NO2 + N2--> HO2NO2 + N2 using near-infrared wavelength-modulation spectroscopy and UV-visible absorption spectroscopy. | THE JOURNAL OF PHYSICAL CHEMISTRY A | Christensen LE, Okumura M, Sander SP, Friedl RR, Miller CE, Sloan JJ | Christensen LE, Okumura M, Sander SP, Friedl RR, Miller CE, Sloan JJ. Measurements of the rate constant of HO2 + NO2 + N2--> HO2NO2 + N2 using near-infrared wavelength-modulation spectroscopy and UV-visible absorption spectroscopy. The Journal of Physical Chemistry A 2003;108(1):80-91. |
R826236 (Final) |
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Journal Article | Experimental and ab initio study of the HO2•CH3OH complex: thermodynamics and kinetics of formation. | THE JOURNAL OF PHYSICAL CHEMISTRY A | Christensen LE, Okumura M, Hansen JC, Sander SP, Francisco JS | Christensen LE, Okumura M, Hansen JC, Sander SP, Francisco JS. Experimental and ab initio study of the HO2•CH3OH complex: thermodynamics and kinetics of formation. The Journal of Physical Chemistry A 2006;110(21):6948-6959. |
R826236 (Final) |
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Journal Article | OH radical yields from the ozone reaction with cycloalkenes. | JOURNAL OF PHYSICAL CHEMISTRY A | Fenske JD, Kuwata KT, Houk KN, Paulson SE | Fenske JD, Kuwata KT, Houk KN, Paulson SE. OH radical yields from the ozone reaction with cycloalkenes. Journal of Physical Chemistry A 2000;104(31):7246-7254. |
R826236 (1999) R826236 (Final) |
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Journal Article | Production of stabilized Criegee intermediates and peroxides in the gas phase ozonolysis of alkenes: 1. Ethene, trans-2-butene, and 2,3-dimethyl-2-butene. | JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES | Hasson AS, Orzechowska G, Paulson SE | Hasson AS, Orzechowska G, Paulson SE. Production of stabilized Criegee intermediates and peroxides in the gas phase ozonolysis of alkenes:1. Ethene, trans-2-butene, and 2,3-dimethyl-2-butene. Journal of Geophysical Research-Atmospheres 2001;106(D24):34131-34142. |
R826236 (Final) |
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Journal Article | Production of stabilized Criegee intermediates and peroxides in the gas phase ozonolysis of alkenes: 2. Asymmetric and biogenic alkenes. | JOURNAL OF GEOPHYSICAL RESEARCH - ATMOSPHERES | Hasson AS, Ho AW, Kuwata KT, Paulson SE | Hasson AS, Ho AW, Kuwata KT, Paulson SE. Production of stabilized Criegee intermediates and peroxides in the gas phase ozonolysis of alkenes:2. Asymmetric and biogenic alkenes. Journal of Geophysical Research-Atmospheres 2001;106(D24):34143-34153. |
R826236 (Final) |
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Journal Article | The gas phase reaction of ozone with 1,3-butadiene: formation yields of some toxic products. | ATMOSPHERIC ENVIRONMENT | Kramp F, Paulson SE | Kramp F, Paulson SE. The gas phase reaction of ozone with 1,3-butadiene:formation yields of some toxic products. Atmospheric Environment 2000;34(1):35-43. |
R826236 (Final) |
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Journal Article | Production of OH radicals from the reactions of C4-C6 internal alkenes and styrenes with ozone in the gas phase. | ATMOSPHERIC ENVIRONMENT | Orzechowska GE, Paulson SE | Orzechowska GE, Paulson SE. Production of OH radicals from the reactions of C4-C6 internal alkenes and styrenes with ozone in the gas phase. Atmospheric Environment 2002;36(3):571-581. |
R826236 (Final) |
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Journal Article | A novel small-ratio relative-rate technique for measuring OH formation yields from the reactions of O3 with alkenes in the gas phase, and its application to the reactions of ethene and propene. | JOURNAL OF PHYSICAL CHEMISTRY | Paulson SE, Fenske JD, Sen AD, Callahan TW | Paulson SE, Fenske JD, Sen AD, Callahan TW. A novel small-ratio relative-rate technique for measuring OH formation yields from the reactions of O3 with alkenes in the gas phase, and its application to the reactions of ethene and propene. Journal of Physical Chemistry A 1999;103(13):2050-2059. |
R826236 (1998) R826236 (Final) |
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Journal Article | OH radical formation from the gas-phase reaction of ozone with terminal alkenes and the relationship between structure and mechanism. | JOURNAL OF PHYSICAL CHEMISTRY A | Paulson SE, Chung MY, Hasson AS | Paulson SE, Chung MY, Hasson AS. OH radical formation from the gas-phase reaction of ozone with terminal alkenes and the relationship between structure and mechanism. Journal of Physical Chemistry A 1999;103(41):8125-8138. |
R826236 (1998) R826236 (Final) |
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Presentation | Pressure dependence of OH formation from ozone reactions with alkenes. | None | Fenske J, Paulson SE | Fenske J, Paulson SE. Pressure dependence of OH formation from ozone reactions with alkenes. Presented at the American Geophysical Union Fall Meeting, San Francisco, CA, December 6-10, 1998. |
R826236 (1998) R826236 (Final) |
not available |
Presentation | OH formation from the ozone reaction with cycloalkenes. | None | Fenske J, Paulson S | Fenske J, Paulson S. OH formation from the ozone reaction with cycloalkenes. Poster presented at the 16th Annual Symposium on Kinetic and Photochemical Processes in the Atmosphere, California State University, Los Angeles, CA, February 18, 1999. |
R826236 (1999) R826236 (Final) |
not available |
Presentation | Computational studies of OH radical production from O3-alkene reactions. | None | Kuwata KT, Paulson SE, Houk KN | Kuwata KT, Paulson SE, Houk KN. Computational studies of OH radical production from O3-alkene reactions. Presented at the American Chemical Society National Meeting, Anaheim, CA, March 21-25, 1999. |
R826236 (1999) R826236 (Final) |
not available |
Presentation | Computational studies of the ozonolysis of 1-alkenes. | None | Kuwata K, Paulson S, Houk K | Kuwata K, Paulson S, Houk K. Computational studies of the ozonolysis of 1-alkenes. Presented at the 16th Annual Symposium on Kinetic and Photochemical Processes in the Atmosphere, California State University, Los Angeles, CA, February 18, 1999. |
R826236 (1999) R826236 (Final) |
not available |
Presentation | The importance of O3-alkene reactions as a source of HOx formation in the boundary layer and development of a structure-activity relationship to predict OH formation yields. | None | Paulson SE | Paulson SE. The importance of O3-alkene reactions as a source of HOx formation in the boundary layer and development of a structure-activity relationship to predict OH formation yields. Presented at the Telluride Workshop on Tropospheric Chemistry, Telluride, CO, August 2-8, 1998. |
R826236 (1998) R826236 (Final) |
not available |
Presentation | Air quality, radicals and ozone-alkene reactions. | None | Paulson SE | Paulson SE. Air quality, radicals and ozone-alkene reactions. Presented to the Department of Chemistry, California State University Long Beach, Long Beach, CA, February 1998. |
R826236 (1998) R826236 (Final) |
not available |
Presentation | OH production, kinetics, and uncertainties: O3-alkene reactions as a source of HOx formation in the boundary layer, and a comparative study of the kinetics and uncertainties of OH reactions with hydrocarbons. | None | Paulson SE | Paulson SE. OH production, kinetics, and uncertainties: O3-alkene reactions as a source of HOx formation in the boundary layer, and a comparative study of the kinetics and uncertainties of OH reactions with hydrocarbons. Presented at the University of California Riverside Program in Environmental Chemistry, Riverside, CA, February 1998. |
R826236 (1998) R826236 (Final) |
not available |
Presentation | OH production, kinetics, and uncertainties: O3-alkene reactions as a source of HOx formation in the boundary layer, and a comparative study of the kinetics and uncertainties of OH reactions with hydrocarbons. | None | Paulson SE | Paulson SE. OH production, kinetics, and uncertainties: O3-alkene reactions as a source of HOx formation in the boundary layer, and a comparative study of the kinetics and uncertainties of OH reactions with hydrocarbons. Presented to the Atmospheric Chemistry Group, Jet Propulsion Laboratory, Pasadena, CA, March 1998. |
R826236 (1998) R826236 (Final) |
not available |
Presentation | The importance of O3-alkene reactions as a source of HOx formation in the boundary layer and development of a structure-activity relationship to predict OH formation yields. | None | Paulson SE | Paulson SE. The importance of O3-alkene reactions as a source of HOx formation in the boundary layer and development of a structure-activity relationship to predict OH formation yields. Presented to the Department of Chemistry, University of California, Santa Barbara, Santa Barbara, CA, November 1998. |
R826236 (1998) R826236 (Final) |
not available |
Presentation | The importance of O3-alkene reactions as a source of HOx formation in the boundary layer and development of a structure-activity relationship to predict OH formation yields. | None | Paulson SE | Paulson SE. The importance of O3-alkene reactions as a source of HOx formation in the boundary layer and development of a structure-activity relationship to predict OH formation yields. Presented to the Departments of Civil/Environmental and Chem/Bio/Materials Engineering, Arizona State University, Tempe, AZ, February 1999. |
R826236 (1999) R826236 (Final) |
not available |
Presentation | The importance of O3-alkene reactions as a course of HOx formation in the boundary layer and development of a structure-activity relationship to predict OH formation yields. | None | Paulson SE | Paulson SE. The importance of O3-alkene reactions as a course of HOx formation in the boundary layer and development of a structure-activity relationship to predict OH formation yields. Presented to the Department of Earth Atmospheric and Space Sciences, University of Michigan, Ann Arbor, MI, January 1999. |
R826236 (1999) R826236 (Final) |
not available |
Presentation | The importance of O3-alkene reactions as a source of HOx formation in the boundary layer. | None | Paulson SE | Paulson SE. The importance of O3-alkene reactions as a source of HOx formation in the boundary layer. Presented at the EUROTRAC Workshop on Chemical Mechanisms in the Atmosphere, Aachen, Germany, September 20-22, 1999. |
R826236 (1999) R826236 (Final) |
not available |
Presentation | Formation of new HOx: ozone-alkene reactions in urban and rural air. | None | Paulson SE | Paulson SE. Formation of new HOx: ozone-alkene reactions in urban and rural air. Presented to the Department of Chemical Engineering, University of Texas, Austin, TX, April 2000. |
R826236 (Final) |
not available |
Presentation | Radicals, acids, and peroxides: ozone-alkene reactions in urban and rural air. | None | Paulson SE | Paulson SE. Radicals, acids, and peroxides:ozone-alkene reactions in urban and rural air. Presented to the Department of Meteorology, University of Utah, Salt Lake City, UT, December 2000. |
R826236 (Final) |
not available |
Presentation | OH production by ozone reactions with isoprene and terpenes. | None | Paulson SE | Paulson SE. OH production by ozone reactions with isoprene and terpenes. Presented at the Gordon Research Conference on Biogenic Hydrocarbons, Ventura, CA, February 27-March 3, 2000. |
R826236 (Final) |
not available |
Presentation | Formation of new HOx: ozone-alkene reactions in urban and rural air. | None | Paulson SE | Paulson SE. Formation of new HOx: ozone-alkene reactions in urban and rural air. Presented to the Department of Chemical Engineering, Princeton University, Princeton, NJ, January 2000. |
R826236 (Final) |
not available |
Presentation | Formation of new HOx: ozone-alkene reactions in urban and rural air. | None | Paulson SE | Paulson SE. Formation of new HOx: ozone-alkene reactions in urban and rural air. Presented to the Department of Earth and Atmospheric Sciences, Harvard University, Cambridge, MA, May 2000. |
R826236 (Final) |
not available |
Presentation | Formation of new HOx: ozone-alkene reactions in urban and rural air. | None | Paulson SE | Paulson SE. Formation of new HOx: ozone-alkene reactions in urban and rural air. Presented at the Gordon Research Conference on Atmospheric Chemistry, Newport, RI, June 17-22, 2001. |
R826236 (Final) |
not available |
Presentation | Radicals, acids, and peroxides: ozone-alkene reactions in urban and rural air. | None | Paulson SE | Paulson SE. Radicals, acids, and peroxides: ozone-alkene reactions in urban and rural air. Presented at the National Oceanographic and Atmospheric Administration, Washington, DC, May 2001. |
R826236 (Final) |
not available |
Presentation | Kinetics and photochemistry of peroxynitric acid in the atmosphere. | None | Sander SP | Sander SP. Kinetics and photochemistry of peroxynitric acid in the atmosphere. Presented at the XXIV Informal Conference on Photochemistry, San Juan, Puerto Rico, April 9-14, 2000. |
R826236 (1999) R826236 (Final) |
not available |
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