Grantee Research Project Results
Final Report: In-Situ Applied Omniphobic Coatings for Water Pipeline Repair and Retrofitting
EPA Contract Number: EPD17040Title: In-Situ Applied Omniphobic Coatings for Water Pipeline Repair and Retrofitting
Investigators: Nakatsuka, Matthew A
Small Business: Oceanit Laboratories, Inc.
EPA Contact: Richards, April
Phase: I
Project Period: September 1, 2017 through February 28, 2018
Project Amount: $100,000
RFA: Small Business Innovation Research (SBIR) - Phase I (2017) RFA Text | Recipients Lists
Research Category: SBIR - Water , Small Business Innovation Research (SBIR)
Description:
One of the greatest domestic challenges currently facing America is how to maintain and repair drinking water infrastructure over the coming years. Corrosion within these pipelines the dual effect of causing mechanical weakness in metal pipe walls, and the development of flow-restricting scales that extrude out from the pipeline surface. Severe corrosion pitting within the walls of the pipeline can lead slow leaks and devastating blow- outs, where the pressure generated by the water flow exceeds the capabilities of the weakened material and the wall buckles. Full replacement of pipelines is an extremely costly expense, and for most municipalities, pipeline maintenance strategies boil down to only addressing pipes which have suffered a complete blow-out.
In this project, Oceanit looked to develop and qualify an economically competitive technique to apply a non-toxic, corrosion resistant coating to the interior of in- place, existing water lines as a method of refurbishment and protection.
Summary/Accomplishments (Outputs/Outcomes):
Oceanit demonstrated that the coating provided superior adhesion and corrosion protection as compared to existing epoxy materials, despite being applied at a thickness of less than 100µm, with minimal surface preparation required, along with abrasion resistance either comparable to or superior to existing coatings (~50mg/1000cycles/1000g Taber Rotary Abrader).
Pipeline interiors coated via the in-situ pigging method showed excellent corrosion resistance, and imparted strong omniphobic (water and oil repellent properties) to the normally hydrophilic pipeline surfaces. Utilizing this pigging method, pipelines of almost any nominal diameter between 4 – 48” inches can be easily coated, and overall lengths exceeding 20 miles of spanned distance should be possible with Oceanit’s application partner.
The pipeline coating material showed no propensity to emit or leach volatile or semi-volatile organic compounds when used as a vessel liner. No regulated heavy metals such as copper or lead were similarly found to be contained within the coating material, whether cured or even in the uncured state, suggesting the material is safe to use and handle. The extremely long pot life (48+ hours), combined with a very short time required to cure in between coatings (30-45 min), leads to a material which has extreme ease of use for application and cleanup, even on significantly rusted and oxidized surfaces.
Oceanit also determined that when properly applied, the coating will function as a complete chemical barrier, preventing the flow of electrons during corrosion, as well as the diffusion and leaching of cytotoxic chemicals from the substrate. Electrochemical impedance spectroscopy showed that even when partially damaged, the presence of the coating significantly reduces the overall corrosion potential of the substrate. Using the standard MTT mitochondrial activity array cell growth and survival showed a near 70% drop after exposure to a cytotoxic substrate (such as glass impregnated with Lysol or cavicide). By comparison, cells exposed to cytotoxic substrates coated with DragXTM showed no change in cellular behavior from a standard non-cytotoxic substrate.
In this Phase I project, Oceanit demonstrated that its omniphobic, in-situ applicable coating imparted corrosion resistance, water repellency and acted as a barrier against potential cytotoxic product leaching. Additionally, the coating proved to be extremely strong and abrasion resistant, even though the coating was applied onto very minimally prepared substrates, and was applied at an extremely thin thickness. Finally, initial toxic component analyte screening showed no significant levels of either VOC, SVOC or lead/copper leaching. As such, the DragXTM coating has demonstrated technical feasibility on a proof-of-concept pilot field application, and is well positioned to attract a commercial partner as part of its phase II effort, as it pursues official certification for potable water transport.
Conclusions:
In contrast to existing methods utilizing cured-in-place-pipe polymer resin sleeves or UV cured epoxies, the novel coating and in-situ application method demonstrated the following advantages
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Coating can be applied via a minimally invasive procedure that can easily scale to any pipeline diameter/length.
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Provided extreme adhesion, corrosion resistance and abrasion resistance to pipeline surfaces despite a far thinner applied thickness (less than 1/10th of existing materials).
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Water-based material showed no cytotoxicity, and VOC and HAP content below EPA mandated levels.
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Material demonstrated ability to prevent leaching of hazardous materials when applied to test surfaces.
The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Conclusions drawn by the principal investigators have not been reviewed by the Agency.