2014 Progress Report: The role of nitrate radicals (NO3) in aerosol life cycle: Secondary organic aerosol formation and aging of atmospheric organic aerosols

EPA Grant Number: R835403
Title: The role of nitrate radicals (NO3) in aerosol life cycle: Secondary organic aerosol formation and aging of atmospheric organic aerosols
Investigators: Ng, Nga Lee
Institution: Georgia Institute of Technology
Current Institution: Georgia Institute of Technology
EPA Project Officer: Chung, Serena
Project Period: April 1, 2013 through March 31, 2016 (Extended to March 31, 2017)
Project Period Covered by this Report: April 1, 2014 through March 31,2015
Project Amount: $300,000
RFA: Anthropogenic Influences on Organic Aerosol Formation and Regional Climate Implications (2012) RFA Text |  Recipients Lists
Research Category: Air Quality and Air Toxics , Global Climate Change , Climate Change , Air

Objective:

The goal of this project is to experimentally determine the extent to which NO3 radicals (formed from anthropogenic NO2 and ozone) affect organic aerosol (OA) loading and composition over its atmospheric lifetime, taking into account secondary organic aerosol (SOA) formation from NO3 oxidation pathway and both daytime and nighttime aging processes. 

Progress Summary:

Work proceeded well during this year. We have performed extensive laboratory experiments to investigate secondary organic aerosol (SOA) and organic nitrate formation from BVOC+NO3. Specifically, we investigated SOA formation from β-pinene+NO3 under dry vs. humid conditions, with ammonium sulfate vs. ammonium sulfate + sulfuric acid seeds, where either “RO2+HO2” or “RO2+NO3” reaction dominates. We used the results from these laboratory studies to evaluate the contributions of monoterpene+NO3 reaction to organic aerosol measured in the southeastern United States, including the Southern Oxidant and Aerosol Study (SOAS) and the Southeastern Center for Air Pollution and Epidemiology (SCAPE) study. Finally, our laboratory results also are used in the development of a coupled gas and aerosol system to describe formation and subsequent aerosol-phase partitioning of organic nitrates in CMAQ. Notable results are:
  1. Investigation of SOA and organic nitrate formation from β-pinene+NO3 under reaction conditions (humidity, seed acidity, peroxy radical fate) relevant to southeast United States.
  2. Determination of the contribution of monoterpenen+NO3 reaction to ambient organic aerosols in the southeast United States.
  3. Incorporation of findings from our laboratory experiments to improve representation and treatment of organic nitrate formation and fates in CMAQ. 

Future Activities:

The main goals of Year 3 activities will be to understand how SOA and organic nitrates formed from NO3+monoterpene evolve during the night-to-day transition. Specific tasks are: 
  1. Study the effects of dilution and temperature change on SOA and organic nitrates formed from NO3+monoterpene
  2. Investigate the effects of photolysis vs. OH oxidation on organic nitrates formed from NO3+monoterpene. 


Journal Articles on this Report : 3 Displayed | Download in RIS Format

Other project views: All 40 publications 14 publications in selected types All 14 journal articles
Type Citation Project Document Sources
Journal Article Boyd CM, Sanchez J, Xu L, Eugene AJ, Nah T, Tuet WY, Guzman MI, Ng NL. Secondary organic aerosol formation from the β-pinene+NO3 system: effect of humidity and peroxy radical fate. Atmospheric Chemistry and Physics 2015;15(13):7497-7522. R835403 (2014)
R835403 (2015)
R835403 (Final)
  • Full-text: Atmospheric Chemistry and Physics-Full-text PDF
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  • Abstract: Atmospheric Chemistry and Physics-Abstract HTML
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  • Other: ResearchGate-Full-text PDF
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  • Journal Article Pye HOT, Luecken DJ, Xu L, Boyd CM, Ng NL, Baker KR, Ayres BR, Bash JO, Baumann K, Carter WPL, Edgerton E, Fry JL, Hutzell WT, Schwede DB, Shepson PB. Modeling the current and future roles of particulate organic nitrates in the Southeastern United States. Environmental Science & Technology 2015;49(24):14195-14203. R835403 (2014)
    R835403 (2015)
    R835403 (Final)
    R835399 (Final)
    R835409 (Final)
    R835410 (2013)
  • Abstract from PubMed
  • Abstract: ES&T-Abstract
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  • Other: ES&T-Full-text PDF
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  • Journal Article Xu L, Guo H, Boyd CM, Klein M, Bougiatioti A, Cerully KM, Hite JR, Isaacman-VanWertz G, Kreisberg NM, Knote C, Olson K, Koss A, Goldstein AH, Hering SV, de Gouw JA, Baumann K, Lee S-H, Nenes A, Weber RJ, Ng NL. Effects of anthropogenic emissions on aerosol formation from isoprene and monoterpenes in the southeastern United States. Proceedings of the National Academy of Sciences of the United States of America 2015;112(1):37-42. R835403 (2014)
    R835403 (2015)
    R835403 (Final)
    R834799 (2015)
    R834799 (2016)
    R834799 (Final)
    R834799C001 (2015)
    R834799C001 (Final)
    R835410 (2013)
  • Full-text from PubMed
  • Abstract from PubMed
  • Associated PubMed link
  • Full-text: PNAS-Full Text PDF
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  • Abstract: PNAS-Abstract & Full Text HTML
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  • Supplemental Keywords:

    organic nitrates, partitioning, semivolatiles, multifunctional oxidation products 

    Relevant Websites:

    School of Chemical & Biomolecular Engineering at Georgia Tech Exit

    Progress and Final Reports:

    Original Abstract
    2013 Progress Report
    2015 Progress Report
    Final Report