Capacitive removal of PFOA and PFOS from Drinking WaterEPA Contract Number: 68HE0D18C0020
Title: Capacitive removal of PFOA and PFOS from Drinking Water
Investigators: Cox, Philip
Small Business: Mainstream Engineering Corporation
EPA Contact: Packard, Benjamin H
Project Period: October 1, 2018 through March 31, 2019
Project Amount: $99,878
RFA: Small Business Innovation Research (SBIR) - Phase I (2018) RFA Text | Recipients Lists
Research Category: Small Business Innovation Research (SBIR) , SBIR - Water , SBIR - Drinking Water and Water Monitoring
Polyfluoroalkyl and perfluoroalkyl compounds (PFCs) have been used commercially since the 1940’s due to their high level of chemical
stability, almost frictionless surface or waterproofing characteristics. Elevated levels of PFCs have been linked to cancer and other
health problems including reproductive and developmental risks. PFOA and PFOS are amongst the most prevalent of the PFCs with
low levels been found in everyone blood especially in areas where the drinking water contains high levels of PFOA/PFOS due to
industrial activity. The EPA has established a limit of less than 70 ng/L. A range of approaches have been investigated to remove PFCs.
While these can be effective they have issues and there is need for improved and flexible solution for removing them from drinking
water and capturing the PFOA/PFOS so it can be destroyed and removed from the environment.
In the Phase I, Mainstream proposes to leverage our high performance capacitive deionization technology for the removal of PFCs
from drinking water. The Mainstream CDI technology has been shown to be an energy efficient, high performance approach for the
removal of low levels of ions from aqueous solutions. In the proposed Phase I, Mainstream will modify our electrode system to
optimize the adsorption of PFOA and PFOS from drinking water. In Phase I, we use of capacitive deionization system to optimize the
adsorption rate and process conditions for the removal and the concentration of the rejected PFOA/PFOS molecules.
Mainstream CDI system allows the rejection of the retained species into a concentrate waste stream thereby increasing the process
efficiency, maximizing environmental benefit and lowering the overall process costs. In Phase II, Mainstream