Grantee Research Project Results
Publications Details for Grant Number R828130
Nearcritical Water as a Reaction Solvent
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| Reference Type | Reference Title | Journal | Author | Citation | Progress Report Year | Document Sources |
|---|---|---|---|---|---|---|
| Book Chapter | Application of high-pressure phase equilibria to the selective oxidation of alcohols over supported platinum catalysts in supercritical carbon dioxide. | None | Glaser R, Williardt J, Bush D, Lazzaroni MJ, Eckert CA | Glaser R, Williardt J, Bush D, Lazzaroni MJ, Eckert CA. Application of high-pressure phase equilibria to the selective oxidation of alcohols over supported platinum catalysts in supercritical carbon dioxide. In: Liu CJ, Mallinson RC, Aresta M, eds. Utilization of Greenhouse Gases, ACS Symposium Series Volume 852. Washington, DC: American Chemical Society, 2003, Chapter 24, pp. 352-364. |
R828130 (Final) |
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| Book Chapter | Catalysis using supercritical or subcritical inert gases under split-phase conditions. | None | Jessop PG, Eckert CA, Liotta CL, Bonilla RJ, Brown JS, Brown RA, Pollet P, Thomas CA, Wheeler C, Wynne D | Jessop PG, Eckert CA, Liotta CL, Bonilla RJ, Brown JS, Brown RA, Pollet P, Thomas CA, Wheeler C, Wynne D. Catalysis using supercritical or subcritical inert gases under split-phase conditions. In: Abrahma A, Moens L, eds. Clean Solvents, ACS Symposium Series Volume 819. Washington, DC: American Chemical Society, 2002, Chapter 8, pp. 97-112. |
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| Journal Article | Acylation of activated aromatics without added acid catalyst. | CHEMICAL COMMUNICATIONS | Brown JS, Glaser R, Liotta CL, Eckert CA | Brown JS, Glaser R, Liotta CL, Eckert CA. Acylation of activated aromatics without added acid catalyst. Chemical Communications 2000;(14):1295-1296. |
R828130 (Final) |
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| Journal Article | Liquid-liquid equilibria for binary mixtures of water plus acetophenone, plus 1-octanol, plus anisole, and plus toluene from 370 K to 550 K | JOURNAL OF CHEMICAL ENGINEERING DATA | Brown JS, Hallett JP, Bush D, Eckert CA | Brown JS, Hallett JP, Bush D, Eckert CA. Liquid-liquid equilibria for binary mixtures of water plus acetophenone, plus 1-octanol, plus anisole, and plus toluene from 370 K to 550 K. Journal of Chemical and Engineering Data 2000;45(5):846-850. |
R828130 (Final) |
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| Journal Article | Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide. | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | Brown RA, Pollet P, McKoon E, Eckert CA, Liotta CL, Jessop PG | Brown RA, Pollet P, McKoon E, Eckert CA, Liotta CL, Jessop PG. Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide. Journal of the American Chemical Society 2001;123(6):1254-1255. |
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| Journal Article | Tuning solvents for sustainable technology. | INDUSTRIAL ENGINEERING AND CHEMISTRY RESEARCH | Eckert CA, Bush D, Brown JS, Liotta CL | Eckert CA, Bush D, Brown JS, Liotta CL. Tuning solvents for sustainable technology. Industrial & Engineering Chemistry Research 2000;39(12):4615-4621. |
R828130 (Final) |
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| Journal Article | Clean solution for chemical synthesis. | CHEMISTRY AND INDUSTRY | Eckert CA, Liotta CL, Brown JS | Eckert CA, Liotta CL, Brown JS. Clean solution for chemical synthesis. Chemistry & Industry 2000;3:94-97. |
R828130 (Final) |
not available |
| Journal Article | Sustainable reactions in tunable solvents. | THE JOURNAL OF PHYSICAL CHEMISTRY B | Eckert CA, Liotta CL, Bush D, Brown JS, Hallett JP | Eckert CA, Liotta CL, Bush D, Brown JS, Hallett JP. Sustainable reactions in tunable solvents. The Journal of Physical Chemistry B 2004;108(47):18108-18118. |
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| Journal Article | Carbon dioxide as a solubility “switch” for the reversible dissolution of highly fluorinated complexes and reagents in organic solvents: application to crystallization. | INORGANIC CHEMISTRY | Jessop PG, Olmstead MM, Ablan CD, Grabenauer M, Sheppard D, Eckert CA, Liotta CL | Jessop PG, Olmstead MM, Ablan CD, Grabenauer M, Sheppard D, Eckert CA, Liotta CL. Carbon dioxide as a solubility “switch” for the reversible dissolution of highly fluorinated complexes and reagents in organic solvents:application to crystallization. Inorganic Chemistry 2002;41(13):3463-3468. |
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| Journal Article | Neoteric solvents for asymmetric hydrogenation: supercritical fluids, ionic liquids, and expanded ionic liquids. | GREEN CHEMISTRY | Jessop PG, Stanley RR, Brown RA, Eckert CA, Liotta CL, Ngo TT, Pollet P | Jessop PG, Stanley RR, Brown RA, Eckert CA, Liotta CL, Ngo TT, Pollet P. Neoteric solvents for asymmetric hydrogenation: supercritical fluids, ionic liquids, and expanded ionic liquids. Green Chemistry 2003;5(2):123-128. |
R828130 (Final) |
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| Journal Article | Photochemical cross-linking of poly(ethylene terephthalate-co-2,6-anthracenedicarboxylate) | MACROMOLECULES | Jones JR, Liotta CL, Collard DM, Schiraldi DA | Jones JR, Liotta CL, Collard DM, Schiraldi DA. Photochemical cross-linking of poly(ethylene terephthalate-co-2,6-anthracenedicarboxylate). Macromolecules 2000;33(5):1640-1645. |
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| Journal Article | Near-critical water: A benign medium for catalytic reactions | INDUSTRIAL ENGINEERING AND CHEMISTRY RESEARCH | Patrick HR, Griffith K, Liotta CL, Eckert CA, Glaser R | Patrick HR, Griffith K, Liotta CL, Eckert CA, Glaser R. Near-critical water: a benign medium for catalytic reactions. Industrial & Engineering Chemistry Research 2001;40(26):6063-6067. |
R828130 (Final) |
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| Journal Article | Polarity and hydrogen-bonding of ambient to near-critical water: Kamlet-Taft solvent parameters | CHEMICAL COMMUNICATIONS | Lu J, Brown JS, Liotta CL, Eckert CA | Lu J, Brown JS, Liotta CL, Eckert CA. Polarity and hydrogen-bonding of ambient to near-critical water: Kamlet-Taft solvent parameters. Chemical Communications 2001;(7):665-666. |
R828130 (Final) |
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| Journal Article | Nearcritical and supercritical ethanol as a benign solvent: polarity and hydrogen-bonding. | FLUID PHASE EQUILIBRIA | Lu J, Boughner EC, Liotta CL, Eckert CA | Lu J, Boughner EC, Liotta CL, Eckert CA. Nearcritical and supercritical ethanol as a benign solvent:polarity and hydrogen-bonding. Fluid Phase Equilibria 2002;198(1):37-49. |
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| Journal Article | Solvatochromic characterization of near-critical water as a benign reaction medium | INDUSTRIAL ENGINEERING AND CHEMISTRY RESEARCH | Lu J, Brown JS, Boughner EC, Liotta CL, Eckert CA | Lu J, Brown JS, Boughner EC, Liotta CL, Eckert CA. Solvatochromic characterization of near-critical water as a benign reaction medium. Industrial & Engineering Chemistry Research 2002;41(12):2835-2841. |
R828130 (Final) |
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| Journal Article | Spectroscopically probing microscopic solvent properties of room-temperature ionic liquids with the addition of carbon dioxide. | THE JOURNAL OF PHYSICAL CHEMISTRY A | Lu J, Liotta CL, Eckert CA | Lu J, Liotta CL, Eckert CA. Spectroscopically probing microscopic solvent properties of room-temperature ionic liquids with the addition of carbon dioxide. The Journal of Physical Chemistry A 2003;107(19):3995-4000. |
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| Journal Article | Spectroscopic measurement of solid solubility in supercritical fluids. | AICHE JOURNAL | Ngo TT, Bush D, Eckert CA, Liotta CL | Ngo TT, Bush D, Eckert CA, Liotta CL. Spectroscopic measurement of solid solubility in supercritical fluids. AIChE Journal 2001;47(11):2566-2572. |
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| Journal Article | Surface modification of polybutadiene facilitated by supercritical carbon dioxide. | JOURNAL OF APPLIED POLYMER SCIENCE | Ngo TT, McCarney J, Brown JS, Lazzaroni MJ, Counts K, Liotta CL, Eckert CA | Ngo TT, McCarney J, Brown JS, Lazzaroni MJ, Counts K, Liotta CL, Eckert CA. Surface modification of polybutadiene facilitated by supercritical carbon dioxide. Journal of Applied Polymer Science 2003;88(2):522-530. |
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| Journal Article | Supercritical fluid impregnation of different azo-dyes into polymer: in situ UV/Vis spectroscopic study. | THE JOURNAL OF SUPERCRITICAL FLUIDS | Ngo TT, Liotta CL, Eckert CA, Kazarian SG | Ngo TT, Liotta CL, Eckert CA, Kazarian SG. Supercritical fluid impregnation of different azo-dyes into polymer: in situ UV/Vis spectroscopic study. The Journal of Supercritical Fluids 2003;27(2):215-221. |
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| Journal Article | Olefin epoxidations using supercritical carbon dioxide and hydrogen peroxide without added metallic catalysts or peroxy acids. | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | Nolen SA, Lu J, Brown JS, Pollet P, Eason BC, Griffith KN, Gläser R, Bush D, Lamb DR, Liotta CL, Eckert CA | Nolen SA, Lu J, Brown JS, Pollet P, Eason BC, Griffith KN, Glaser R, Bush D, Lamb DR, Liotta CL, Eckert CA. Olefin epoxidations using supercritical carbon dioxide and hydrogen peroxide without added metallic catalysts or peroxy acids. Industrial & Engineering Chemistry Research 2002;41(3):316-323. |
R828130 (Final) |
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| Journal Article | The catalytic opportunities of near-critical water: a benign medium for conventionally acid and base catalyzed condensations for organic synthesis | GREEN CHEMISTRY | Nolen SA, Liotta CL, Eckert CA, Glaser R | Nolen SA, Liotta CL, Eckert CA, Glaser R. The catalytic opportunities of near-critical water: a benign medium for conventionally acid and base catalyzed condensations for organic synthesis. Green Chemistry 2003;5(5):663-669. |
R828130 (Final) |
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| Journal Article | In situ formation of alkylcarbonic acids with CO2. | THE JOURNAL OF PHYSICAL CHEMISTRY A | West KN, Wheeler C, McCarney JP, Griffith KN, Bush D, Liotta CL, Eckert CA. | West KN, Wheeler C, McCarney JP, Griffith KN, Bush D, Liotta CL, Eckert CA. In situ formation of alkylcarbonic acids with CO2. The Journal of Physical Chemistry A 2001;105(16):3947-3948. |
R828130 (Final) |
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| Journal Article | Ionic liquids as catalytic green solvents for nucleophilic displacement reactions. | CHEMICAL COMMUNICATIONS | Wheeler C, West KN, Liotta CL, Eckert CA | Wheeler C, West KN, Liotta CL, Eckert CA. Ionic liquids as catalytic green solvents for nucleophilic displacement reactions. Chemical Communications 2001;(10):887-888. |
R828130 (Final) |
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| Journal Article | Phase-transfer-catalyzed alkylation of phenylacetonitrile in supercritical ethane. | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | Wheeler C, Lamb DR, Jayachandran JP, Hallett JP, Liotta CL, Eckert CA | Wheeler C, Lamb DR, Jayachandran JP, Hallett JP, Liotta CL, Eckert CA. Phase-transfer-catalyzed alkylation of phenylacetonitrile in supercritical ethane.Industrial & Engineering Chemistry Research 2002;41(7):1763-1767. |
R828130 (Final) |
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| Journal Article | Phase-transfer catalyst separation by CO2 enhanced aqueous extraction. | CHEMICAL COMMUNICATIONS | Xie X, Brown JS, Joseph PJ, Liotta CL, Eckert CA | Xie X, Brown JS, Joseph PJ, Liotta CL, Eckert CA. Phase-transfer catalyst separation by CO2 enhanced aqueous extraction. Chemical Communications 2002;(10):1156-1157. |
R828130 (Final) |
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| Presentation | Catalysis with environmentally benign solvents at elevated temperature and pressure. | None | Brown J, Hallett JP, Glaser R, Liotta CL | Brown J, Hallett JP, Glaser R, Liotta CL. Catalysis with environmentally benign solvents at elevated temperature and pressure. Presented at the American Institute of Chemical Engineers Annual Meeting, Los Angeles, CA, November 2000. |
R828130 (Final) |
not available |
| Presentation | Environmentally benign chemical processing alternatives using acetic acid and nearcritical water. | None | Brown J, Glaser R, Eckert CA, Liotta CL | Brown J, Glaser R, Eckert CA, Liotta CL. Environmentally benign chemical processing alternatives using acetic acid and nearcritical water. Presented at the Green Chemistry Meeting, Washington, DC, June 2000. |
R828130 (Final) |
not available |
| Presentation | Expanded solvents for sustainable technology. | None | Eckert CA | Eckert CA. Expanded solvents for sustainable technology. Presented at the Laboratoire de Thermodynamique des Equilibres entre Phases, Centre Reacteurs et Processus, Ecole Nationale Superieure des Mines de Paris, Fontainebleau, France, April 12, 2002. |
R828130 (Final) |
not available |
| Presentation | Expanded solvents for sustainable technology. | None | Eckert CA | Eckert CA. Expanded solvents for sustainable technology. Presented at the Chemical Engineering Department, University of Illinois, Chicago, IL, February 21, 2002. |
R828130 (Final) |
not available |
| Presentation | Expanded solvents for sustainable technology. | None | Eckert CA | Eckert CA. Expanded solvents for sustainable technology. Presented at the Chemical Engineering Department, University of Kansas, Lawrence, KS, October 23, 2001. |
R828130 (Final) |
not available |
| Presentation | Nontraditional solvents for sustainable chemical processes. | None | Eckert CA, Liotta CL | Eckert CA, Liotta CL. Nontraditional solvents for sustainable chemical processes. Presented at the Midwest American Chemical Society Meeting, Lawrence, KS, October 24, 2002. |
R828130 (Final) |
not available |
| Presentation | Solvent selection for separations and reactions. | None | Eckert CA, Bush D, Lazzaroni MJ | Eckert CA, Bush D, Lazzaroni MJ. Solvent selection for separations and reactions. Presented to the Dow Chemical Company, Midland, MI, October 9, 2002. |
R828130 (Final) |
not available |
| Presentation | Tuning of chemical reactions with expanded solvents. | None | Eckert CA, Glaser R, Brown JS | Eckert CA, Glaser R, Brown JS. Tuning of chemical reactions with expanded solvents. Presented at the 5th Conference on Supercritical Fluids and Their Applications, Associanzione Italiana di Ingregneria Chimica, Verona, Italy, June 1999. |
R828130 (Final) |
not available |
| Presentation | Base-catalyzed reactions in near-critical water for environmentally benign chemical processing. | None | Glaser R, Brown JS, Liotta CL, Eckert CA | Glaser R, Brown JS, Liotta CL, Eckert CA. Base-catalyzed reactions in near-critical water for environmentally benign chemical processing. Presented at the 217th American Chemical Society National Meeting, Anaheim, CA, March 1999. |
R828130 (Final) |
not available |
| Presentation | High temperature water/organic liquid-liquid equilibria. | None | Hallett J, Bush D, Eckert CA, Brown J | Hallett J, Bush D, Eckert CA, Brown J. High temperature water/organic liquid-liquid equilibria. Presented at the American Institute of Chemical Engineers Annual Meeting, Los Angeles, CA, November 2000. |
R828130 (Final) |
not available |
| Presentation | Organic/water phase equilibria at high temperature. | None | Hallett J, Bush D, Eckert CA, Brown J | Hallett J, Bush D, Eckert CA, Brown J. Organic/water phase equilibria at high temperature. Presented at the National Institute of Standards and Technology, Boulder, CO, June 2000. |
R828130 (Final) |
not available |
| Presentation | Acid- vs base-catalyzed ester hydrolysis in nearcritical water. | None | Lesutis HP, Glaser R, Eckert CA, Liotta CL | Lesutis HP, Glaser R, Eckert CA, Liotta CL. Acid- vs base-catalyzed ester hydrolysis in nearcritical water. Presented at the American Institute of Chemical Engineers Annual Meeting, Dallas, TX, November 2, 1999. |
R828130 (Final) |
not available |
| Presentation | Nearcritical water: a benign medium for catalytic reactions. | None | Lesutis HP, Glaser R, Griffith KN, Eckert CA, Liotta CL | Lesutis HP, Glaser R, Griffith KN, Eckert CA, Liotta CL. Nearcritical water: a benign medium for catalytic reactions. Presented at the 5th International Symposium on Supercritical Fluids, Atlanta, GA, April 2000. |
R828130 (Final) |
not available |
| Presentation | Self-neutralizing catalysis in nearcritical water. | None | Lesutis HP, Glaser R, Griffith K, Eckert CA, Liotta CL | Lesutis HP, Glaser R, Griffith K, Eckert CA, Liotta CL. Self-neutralizing catalysis in nearcritical water. Presented at the Green Chemistry Meeting, Washington, DC, June 2000. |
R828130 (Final) |
not available |
| Presentation | Green replacement solvents: environmentally benign solvent systems for chemical reactions and processes. | None | Liotta CL, Brown JS, West KN, Hallett JP, McCarnery JP, Nolen SA, Culp CW, Griffith K, Eckert CA, Glaser R | Liotta CL, Brown JS, West KN, Hallett JP, McCarnery JP, Nolen SA, Culp CW, Griffith K, Eckert CA, Glaser R. Green replacement solvents: environmentally benign solvent systems for chemical reactions and processes. Presented at the Southeast/Southwest Regional American Chemical Society Meeting, New Orleans, LA, December 5, 2000. |
R828130 (Final) |
not available |
| Presentation | Nearcritical water as a process solvent. | None | Lu J, Hallett J, Eckert CA, Bush D | Lu J, Hallett J, Eckert CA, Bush D. Nearcritical water as a process solvent. Presented at the 16th International Union of Pure and Applied Chemistry Conference on Chemical Thermodyamics, Halifax, Nova Scotia, Canada, August 2000. |
R828130 (Final) |
not available |
| Presentation | Nearcritical water as a reaction medium. | None | Lu J, Brown JS, Nolen SA, Hallett JP, Eckert CA, Liotta CL | Lu J, Brown JS, Nolen SA, Hallett JP, Eckert CA, Liotta CL. Nearcritical water as a reaction medium. Presented at the 10th International Symposium on Supercritical Fluid Chromatography, Extraction, and Processing, Myrtle Beach, SC, August 23, 2001. |
R828130 (Final) |
not available |
| Presentation | Neutral acid-catalytic reactions in nearcritical water. | None | Lu J, Brown JS, Eckert CA, Liotta CL | Lu J, Brown JS, Eckert CA, Liotta CL. Neutral acid-catalytic reactions in nearcritical water. Presented at the 5th Annual Green Chemistry and Engineering Conference, Washington, DC, June 26-28, 2001. |
R828130 (Final) |
not available |
| Presentation | Phase equilibria for near-critical water. | None | Lu J, Brown JS, Eckert CA, Liotta CL | Lu J, Brown JS, Eckert CA, Liotta CL. Phase equilibria for near-critical water. Presented at the American Institute of Chemical Engineers Annual Meeting, Dallas, TX, November 2, 1999. |
R828130 (Final) |
not available |
| Presentation | Solvatochromic parameters for nearcritical water. | None | Lu J, Brown JS, West KN, Eckert CA, Liotta CL | Lu J, Brown JS, West KN, Eckert CA, Liotta CL. Solvatochromic parameters for nearcritical water. Presented at the National Institute of Standards and Technology, Boulder, CO, June 2000. |
R828130 (Final) |
not available |
| Presentation | Solvent effects on chemical reactions in nearcritical water. | None | Lu J, Brown JS, Bush D, Eckert CA, Liotta CL | Lu J, Brown JS, Bush D, Eckert CA, Liotta CL. Solvent effects on chemical reactions in nearcritical water. Presented at the American Institute of Chemical Engineers Annual Meeting, Los Angeles, CA, November 2000. |
R828130 (Final) |
not available |
| Presentation | Solvatochromic properties of near- and supercritical ethanol and nearcritical acetic acid. | None | Lu J, Eckert CA, Liotta CL | Lu J, Eckert CA, Liotta CL. Solvatochromic properties of near- and supercritical ethanol and nearcritical acetic acid. Presented at the American Institute of Chemical Engineers Annual Meeting, Los Angeles, CA, November 2000. |
R828130 (Final) |
not available |
| Proceedings | Base-catalyzed reactions in near-critical water for environmentally benign chemical processing. | None | Glaser R, Brown JS, Liotta CL, Eckert CA | Glaser R, Brown JS, Liotta CL, Eckert CA. Base-catalyzed reactions in near-critical water for environmentally benign chemical processing. In: Proceedings of the 217th American Chemical Society National Meeting Symposium Preprint, Chemistry of Renewable Fuels and Chemicals, Anaheim, CA, March 1999, Vol. 44, No. 2, pp. 385-388. |
R828130 (Final) |
not available |
The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Conclusions drawn by the principal investigators have not been reviewed by the Agency.