Grantee Research Project Results
Journal Publications Details for Grant Number R828130
Nearcritical Water as a Reaction Solvent
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| Reference Type | Reference Title | Journal | Author | Citation | Progress Report Year | Document Sources |
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| Journal Article | Acylation of activated aromatics without added acid catalyst. | CHEMICAL COMMUNICATIONS | Brown JS, Glaser R, Liotta CL, Eckert CA | Brown JS, Glaser R, Liotta CL, Eckert CA. Acylation of activated aromatics without added acid catalyst. Chemical Communications 2000;(14):1295-1296. |
R828130 (Final) |
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| Journal Article | Liquid-liquid equilibria for binary mixtures of water plus acetophenone, plus 1-octanol, plus anisole, and plus toluene from 370 K to 550 K | JOURNAL OF CHEMICAL ENGINEERING DATA | Brown JS, Hallett JP, Bush D, Eckert CA | Brown JS, Hallett JP, Bush D, Eckert CA. Liquid-liquid equilibria for binary mixtures of water plus acetophenone, plus 1-octanol, plus anisole, and plus toluene from 370 K to 550 K. Journal of Chemical and Engineering Data 2000;45(5):846-850. |
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| Journal Article | Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide. | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | Brown RA, Pollet P, McKoon E, Eckert CA, Liotta CL, Jessop PG | Brown RA, Pollet P, McKoon E, Eckert CA, Liotta CL, Jessop PG. Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide. Journal of the American Chemical Society 2001;123(6):1254-1255. |
R828130 (Final) |
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| Journal Article | Tuning solvents for sustainable technology. | INDUSTRIAL ENGINEERING AND CHEMISTRY RESEARCH | Eckert CA, Bush D, Brown JS, Liotta CL | Eckert CA, Bush D, Brown JS, Liotta CL. Tuning solvents for sustainable technology. Industrial & Engineering Chemistry Research 2000;39(12):4615-4621. |
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| Journal Article | Clean solution for chemical synthesis. | CHEMISTRY AND INDUSTRY | Eckert CA, Liotta CL, Brown JS | Eckert CA, Liotta CL, Brown JS. Clean solution for chemical synthesis. Chemistry & Industry 2000;3:94-97. |
R828130 (Final) |
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| Journal Article | Sustainable reactions in tunable solvents. | THE JOURNAL OF PHYSICAL CHEMISTRY B | Eckert CA, Liotta CL, Bush D, Brown JS, Hallett JP | Eckert CA, Liotta CL, Bush D, Brown JS, Hallett JP. Sustainable reactions in tunable solvents. The Journal of Physical Chemistry B 2004;108(47):18108-18118. |
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| Journal Article | Carbon dioxide as a solubility “switch” for the reversible dissolution of highly fluorinated complexes and reagents in organic solvents: application to crystallization. | INORGANIC CHEMISTRY | Jessop PG, Olmstead MM, Ablan CD, Grabenauer M, Sheppard D, Eckert CA, Liotta CL | Jessop PG, Olmstead MM, Ablan CD, Grabenauer M, Sheppard D, Eckert CA, Liotta CL. Carbon dioxide as a solubility “switch” for the reversible dissolution of highly fluorinated complexes and reagents in organic solvents:application to crystallization. Inorganic Chemistry 2002;41(13):3463-3468. |
R828130 (Final) |
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| Journal Article | Neoteric solvents for asymmetric hydrogenation: supercritical fluids, ionic liquids, and expanded ionic liquids. | GREEN CHEMISTRY | Jessop PG, Stanley RR, Brown RA, Eckert CA, Liotta CL, Ngo TT, Pollet P | Jessop PG, Stanley RR, Brown RA, Eckert CA, Liotta CL, Ngo TT, Pollet P. Neoteric solvents for asymmetric hydrogenation: supercritical fluids, ionic liquids, and expanded ionic liquids. Green Chemistry 2003;5(2):123-128. |
R828130 (Final) |
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| Journal Article | Photochemical cross-linking of poly(ethylene terephthalate-co-2,6-anthracenedicarboxylate) | MACROMOLECULES | Jones JR, Liotta CL, Collard DM, Schiraldi DA | Jones JR, Liotta CL, Collard DM, Schiraldi DA. Photochemical cross-linking of poly(ethylene terephthalate-co-2,6-anthracenedicarboxylate). Macromolecules 2000;33(5):1640-1645. |
R828130 (Final) |
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| Journal Article | Near-critical water: A benign medium for catalytic reactions | INDUSTRIAL ENGINEERING AND CHEMISTRY RESEARCH | Patrick HR, Griffith K, Liotta CL, Eckert CA, Glaser R | Patrick HR, Griffith K, Liotta CL, Eckert CA, Glaser R. Near-critical water: a benign medium for catalytic reactions. Industrial & Engineering Chemistry Research 2001;40(26):6063-6067. |
R828130 (Final) |
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| Journal Article | Polarity and hydrogen-bonding of ambient to near-critical water: Kamlet-Taft solvent parameters | CHEMICAL COMMUNICATIONS | Lu J, Brown JS, Liotta CL, Eckert CA | Lu J, Brown JS, Liotta CL, Eckert CA. Polarity and hydrogen-bonding of ambient to near-critical water: Kamlet-Taft solvent parameters. Chemical Communications 2001;(7):665-666. |
R828130 (Final) |
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| Journal Article | Nearcritical and supercritical ethanol as a benign solvent: polarity and hydrogen-bonding. | FLUID PHASE EQUILIBRIA | Lu J, Boughner EC, Liotta CL, Eckert CA | Lu J, Boughner EC, Liotta CL, Eckert CA. Nearcritical and supercritical ethanol as a benign solvent:polarity and hydrogen-bonding. Fluid Phase Equilibria 2002;198(1):37-49. |
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| Journal Article | Solvatochromic characterization of near-critical water as a benign reaction medium | INDUSTRIAL ENGINEERING AND CHEMISTRY RESEARCH | Lu J, Brown JS, Boughner EC, Liotta CL, Eckert CA | Lu J, Brown JS, Boughner EC, Liotta CL, Eckert CA. Solvatochromic characterization of near-critical water as a benign reaction medium. Industrial & Engineering Chemistry Research 2002;41(12):2835-2841. |
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| Journal Article | Spectroscopically probing microscopic solvent properties of room-temperature ionic liquids with the addition of carbon dioxide. | THE JOURNAL OF PHYSICAL CHEMISTRY A | Lu J, Liotta CL, Eckert CA | Lu J, Liotta CL, Eckert CA. Spectroscopically probing microscopic solvent properties of room-temperature ionic liquids with the addition of carbon dioxide. The Journal of Physical Chemistry A 2003;107(19):3995-4000. |
R828130 (Final) |
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| Journal Article | Spectroscopic measurement of solid solubility in supercritical fluids. | AICHE JOURNAL | Ngo TT, Bush D, Eckert CA, Liotta CL | Ngo TT, Bush D, Eckert CA, Liotta CL. Spectroscopic measurement of solid solubility in supercritical fluids. AIChE Journal 2001;47(11):2566-2572. |
R828130 (Final) |
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| Journal Article | Surface modification of polybutadiene facilitated by supercritical carbon dioxide. | JOURNAL OF APPLIED POLYMER SCIENCE | Ngo TT, McCarney J, Brown JS, Lazzaroni MJ, Counts K, Liotta CL, Eckert CA | Ngo TT, McCarney J, Brown JS, Lazzaroni MJ, Counts K, Liotta CL, Eckert CA. Surface modification of polybutadiene facilitated by supercritical carbon dioxide. Journal of Applied Polymer Science 2003;88(2):522-530. |
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| Journal Article | Supercritical fluid impregnation of different azo-dyes into polymer: in situ UV/Vis spectroscopic study. | THE JOURNAL OF SUPERCRITICAL FLUIDS | Ngo TT, Liotta CL, Eckert CA, Kazarian SG | Ngo TT, Liotta CL, Eckert CA, Kazarian SG. Supercritical fluid impregnation of different azo-dyes into polymer: in situ UV/Vis spectroscopic study. The Journal of Supercritical Fluids 2003;27(2):215-221. |
R828130 (Final) |
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| Journal Article | Olefin epoxidations using supercritical carbon dioxide and hydrogen peroxide without added metallic catalysts or peroxy acids. | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | Nolen SA, Lu J, Brown JS, Pollet P, Eason BC, Griffith KN, Gläser R, Bush D, Lamb DR, Liotta CL, Eckert CA | Nolen SA, Lu J, Brown JS, Pollet P, Eason BC, Griffith KN, Glaser R, Bush D, Lamb DR, Liotta CL, Eckert CA. Olefin epoxidations using supercritical carbon dioxide and hydrogen peroxide without added metallic catalysts or peroxy acids. Industrial & Engineering Chemistry Research 2002;41(3):316-323. |
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| Journal Article | The catalytic opportunities of near-critical water: a benign medium for conventionally acid and base catalyzed condensations for organic synthesis | GREEN CHEMISTRY | Nolen SA, Liotta CL, Eckert CA, Glaser R | Nolen SA, Liotta CL, Eckert CA, Glaser R. The catalytic opportunities of near-critical water: a benign medium for conventionally acid and base catalyzed condensations for organic synthesis. Green Chemistry 2003;5(5):663-669. |
R828130 (Final) |
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| Journal Article | In situ formation of alkylcarbonic acids with CO2. | THE JOURNAL OF PHYSICAL CHEMISTRY A | West KN, Wheeler C, McCarney JP, Griffith KN, Bush D, Liotta CL, Eckert CA. | West KN, Wheeler C, McCarney JP, Griffith KN, Bush D, Liotta CL, Eckert CA. In situ formation of alkylcarbonic acids with CO2. The Journal of Physical Chemistry A 2001;105(16):3947-3948. |
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| Journal Article | Ionic liquids as catalytic green solvents for nucleophilic displacement reactions. | CHEMICAL COMMUNICATIONS | Wheeler C, West KN, Liotta CL, Eckert CA | Wheeler C, West KN, Liotta CL, Eckert CA. Ionic liquids as catalytic green solvents for nucleophilic displacement reactions. Chemical Communications 2001;(10):887-888. |
R828130 (Final) |
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| Journal Article | Phase-transfer-catalyzed alkylation of phenylacetonitrile in supercritical ethane. | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | Wheeler C, Lamb DR, Jayachandran JP, Hallett JP, Liotta CL, Eckert CA | Wheeler C, Lamb DR, Jayachandran JP, Hallett JP, Liotta CL, Eckert CA. Phase-transfer-catalyzed alkylation of phenylacetonitrile in supercritical ethane.Industrial & Engineering Chemistry Research 2002;41(7):1763-1767. |
R828130 (Final) |
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| Journal Article | Phase-transfer catalyst separation by CO2 enhanced aqueous extraction. | CHEMICAL COMMUNICATIONS | Xie X, Brown JS, Joseph PJ, Liotta CL, Eckert CA | Xie X, Brown JS, Joseph PJ, Liotta CL, Eckert CA. Phase-transfer catalyst separation by CO2 enhanced aqueous extraction. Chemical Communications 2002;(10):1156-1157. |
R828130 (Final) |
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The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Conclusions drawn by the principal investigators have not been reviewed by the Agency.