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EFFECTS OF PH AND COMPETING ANIONS ON THE SOLUTION SPECIATION OF ARSENIC BY ION EXCHANGE RESINS
Citation:
Impellitteri**, C A., J A. Ryan*, S R. AlAbed*, K G. Scheckel*, AND P M. Randall*. EFFECTS OF PH AND COMPETING ANIONS ON THE SOLUTION SPECIATION OF ARSENIC BY ION EXCHANGE RESINS. American Chemical Society 225th Annual Meeting, New Orleans, LA, 3/23-27/2003.
Description:
Anion-exchange resins (AER) are used to differentiate As(V) and As(III) by retaining As(V) and allowing As(III) to pass through. AERs allow rapid speciation of As in the field which precludes the effects sample preservation on As speciation. Aqueous environmental samples contain anions that may interfere with the speciation of As. This study compares the speciation of As by two commercially available AERs. A silica based AER was selected for further study. As(V) and As(III) were passed through the AER in the presence of NO3-, SO42-, HPO42-, Cl-, and HCO3-at pH 4, 6, and 8. Recoveries of As species in mixed systems range between 90 to 100%. Breakthrough curves for As(V) are presented which allow calculation of loading rates. HPO42- has the greatest effect on the speciation of As by AER.