You are here:
CALIX[6]ARENE DERIVATIVES BEARING SULFONATE AND ALKYL GROUPS AS SURFACTANTS IN SC(OTF)3-CATALYZED MUKAIYAMA ALDOL REACTIONS IN WATER. (R822668)
Citation:
Tian, H. Y., Y. J. Chen, D. Wang, C. C. Zeng, AND C. J. Li. CALIX[6]ARENE DERIVATIVES BEARING SULFONATE AND ALKYL GROUPS AS SURFACTANTS IN SC(OTF)3-CATALYZED MUKAIYAMA ALDOL REACTIONS IN WATER. (R822668). TETRAHEDRON LETTERS. American Chemical Society, Washington, DC, 41(15):2529-2532, (2000).
Description:
Abstract
Amphiphilic calix[6]arene derivatives 1a¯b were found to be efficient surfactants for Sc(OTf)3-catalyzed Mukaiyama aldol reaction of silyl enol ethers with aldehydes in water. The results indicated that a hydrophobic microenvironment was formed in the reaction system, which is favorable to stabilize some labile silyl enol ethers and thus promotes the reactions.
Record Details:
Record Type:DOCUMENT( JOURNAL/ PEER REVIEWED JOURNAL)
Product Published Date:04/01/2000
Record Last Revised:12/22/2005
Record ID:
69042