Citation:

Tian, H. Y., Y. J. Chen, D. Wang, Y. P. Bu, AND C. J. Li. THE EFFECTS OF AROMATIC AND ALIPHATIC ANIONIC SURFACTANTS ON SC(OTF)3-CATALYZED MUKAIYAMA ALDOL REACTION IN WATER. (R822668). TETRAHEDRON LETTERS. American Chemical Society, Washington, DC, 42(10):1803-1805, (2001).

Description:

Abstract

Aromatic (2c and 2d) and aliphatic (2a and 2b) anionic surfactants were employed in Sc(OTf)₃-catalyzed aldol reactions of some labile silyl enol ethers (3a and 3b) with aromatic aldehydes in water. The results indicated that the aromatic surfactants have a better ability to inhibit the hydrolysis of labile silyl enol ethers and promote the aldol reaction, leading to higher yields of aldol adducts.

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Record Details:

Record Type:DOCUMENT( JOURNAL/ PEER REVIEWED JOURNAL)

Product Published Date:03/01/2001

Record Last Revised:12/22/2005

Record ID: 69038

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Document IDs:

EPA Number :R822668