Citation:

Yang, X. F., M. Wang, R S. Varma*, AND C. J. Li. ALDOL- AND MANNICH-TYPE REACTIONS VIA IN SITU OLEFIN MIGRATION IN IONIC LIQUID. Smith, III, A.B. (ed.), ORGANIC LETTERS. American Chemical Society, Washington, DC, 5(5):657-660, (2003).

Description:

An aldol-type and a Mannich-type reaction via the cross-coupling of aldehydes and imines with allylic alcohols catalyzed by RuCl2(PPh3)3 was developed with ionic liquid as the solvent. The solvent/catalyst system could be reused for at least five times with no loss of reactivity.

Record Details:

Record Type:DOCUMENT( JOURNAL/ PEER REVIEWED JOURNAL)

Product Published Date:03/06/2003

Record Last Revised:12/22/2005

Record ID: 65761

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Related Organizations:

Role :OWNER

Organization Name :US ENVIRONMENTAL PROTECTION AGENCY

Organization Name :OFFICE OF RESEARCH AND DEVELOPMENT

Organization Name :NATIONAL RISK MANAGEMENT RESEARCH LABORATORY

Organization Name :SUSTAINABLE TECHNOLOGY DIVISION

Document IDs:

EPA Number :EPA/600/J-03/186