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ESTIMATING DISSOLVED ORGANIC CARBON PARTITION COEFFICIENTS FOR NONIONIC ORGANIC CHEMICALS
Citation:
Burkhard, L P. ESTIMATING DISSOLVED ORGANIC CARBON PARTITION COEFFICIENTS FOR NONIONIC ORGANIC CHEMICALS. ENVIRONMENTAL SCIENCE & TECHNOLOGY 34(22):4663-4668, (2000).
Description:
A literature search was performed for dissolved organic carbon/water partition coefficients for nonionic chemicals (Kdoc) and Kdoc data was taken from more than sixty references. The Kdoc data were evaluated as a function of the n-octanol/water partition coefficients (Kow). A predictive relationship of Kdoc = 0.06 Kow with 95% confidence limits of a factor or 20 in either direction was developed using Kdoc data based upon naturally occurring dissolved organic carbon. Inclusion of Kdoc data for Aldrich humic acid, a reagent grade organic carbon, resulted in a slightly different predictive relationship of Kdoc = 0.09 Kow with 95% confidence limits of a factor of 17 in either direction. The large uncertainties in these relationships are, in part, caused by the variability in structure and composition of dissolved organic carbon (DOC) in sediments, soils and surface waters, and this variability is not accounted for by the hydrophobicity parameter. For individual chemicals, ranges in Kdoc values approaching two orders of magnitude were observed among investigations using Aldrich humic acid as the DOC. These large ranges of Kdoc values suggest that measurement techniques are also, in part, responsible for the large uncertainties in these relationships.