Science Inventory

VANADIUM PHOSPHORUS OXIDE AS AN EFFICIENT CATALYST FOR HYDROCARBON OXIDATIONS USING HYDROGEN PEROXIDE

Citation:

Pillai**, U R. AND E SahleDemessie*. VANADIUM PHOSPHORUS OXIDE AS AN EFFICIENT CATALYST FOR HYDROCARBON OXIDATIONS USING HYDROGEN PEROXIDE. Crabtree, R.H. (ed.), NEW JOURNAL OF CHEMISTRY. Royal Society of Chemistry, Cambridge, Uk, 27(3):525-528, (2003).

Description:

Calcined vanadium phosphorus oxide (VPO) prepared by an organic route is found to be an efficient catalyst for the oxidation of various alkanes such as cyclopentane, cyclohexane, n-hexane, cycloheptane, cyclooctane, cyclodecane and adamantane in acetonitrile solvent using the environmentally benign oxidant, hydrogen peroxide, where the oxidation mechanism is believed to involve a reversible V4+/V5+ redox cycle.

Record Details:

Record Type:DOCUMENT( JOURNAL/ PEER REVIEWED JOURNAL)
Product Published Date:02/04/2003
Record Last Revised:12/22/2005
Record ID: 64371