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FUNDAMENTAL COMBUSTION RESEARCH APPLIED TO POLLUTION FORMATION. VOLUME 1. FCR PROGRAM OVERVIEW AND GAS-PHASE CHEMISTRY
Citation:
Seeker, W., M. Heap, T. Tyson, J. Kramlich, AND T. Corley. FUNDAMENTAL COMBUSTION RESEARCH APPLIED TO POLLUTION FORMATION. VOLUME 1. FCR PROGRAM OVERVIEW AND GAS-PHASE CHEMISTRY. U.S. Environmental Protection Agency, Washington, D.C., EPA/600/7-85/048.
Description:
The report is the first in a series of four, documenting research performed under EPA's Fundamental Combustion Research (FCR) program. It is divided in two: Part A is a program overview and an introduction to the series; and Part B documents research performed in the gas-phase chemistry area. The primary focus of the FCR program is to better understand phenomena controlling formation of nitrogen oxides (NOx) from stationary combustion sources. A major effort was mounted to develop a set of elementary reactions describing NOx formation, particularly those involving fuel-bound nitrogen species. Since NOx formation is intimately coupled with the heat release process, it was essential that the assembled reaction set also accurately describe hydrocarbon oxidation. A methodology was employed where-by the kinetic set was systematically developed and evaluated. Development began with the simple hydrogen/air system and progressed in verified steps to methane/air. Each step involved comparison of prediction with available experimental data. Behavior at both short and long characteristics times was evaluated.