You are here:
OZONE PRECURSOR LEVELS AND RESPONSES TO EMISSIONS REDUCTIONS:ANALYSIS OF REGIONAL OXIDANT MODEL RESULTS
Citation:
Milford, J., D. Gao, A. Zafirakou, AND T. Pierce. OZONE PRECURSOR LEVELS AND RESPONSES TO EMISSIONS REDUCTIONS:ANALYSIS OF REGIONAL OXIDANT MODEL RESULTS. U.S. Environmental Protection Agency, Washington, D.C., EPA/600/J-95/271, 1994.
Description:
An analysis of results from the Regional Oxidant Modeling for Northeast Transport (ROMNET) study (U.S. EPA, 1991, EPA-450/4-91-002a) has investigated the chemical conditions under which air quality was predicted to improve with reductions in ROG and/or NOx emissions, or with changes in the composition of ROG emissions. he ROMNET simulations used emissions projected to the year 2005, with meteorological conditions from July 1988. redicted concentrations of PAN, HNO3, H2O2 and HCHO are shown along with O3 for 2005 base case, allowing limited comparisons to be made with field observations and results from other modeling studies. redicted secondary pollutant concentrations indicate an unusual degree of photochemical activity over much of the model domain, directionally consistent with the extreme nature of the July 1988 episode. educing NOx emissions was predicted to reduce O3 in grid cells in which reactive nitrogen (NOy) concentrations were below about 25 ppb, but to be counterproductive for some cells with higher NOy. he New York City area where NOx control was predicted to be counterproductive was characterized by very high NOx to NOy ratios. zone was relatively insensitive to ROG controls in grid cells with NOY concentrations below 5-10 ppb. omparison of unweighted ROG concentrations with concentrations weighted by HO rate constants (i.e. reactivity) showed that the latter varied less across locations. redicted spatial gradients of NOy were generally sharper than those of reactivity-weighted ROG, supporting a dominant role for variations in NOY in controlling the sensitivity of ozone to its precursors. eductions in reactivity-weighted ROG achieved with composition changes were similar to reductions achieved with ROG emissions cuts, explaining the similar response of ozone to these two control strategies.