Citation:

Sa, S., M. Gawande, A. Velhinho, J. Veiga, N. Bundaleski, J. Triqueiro, A. Tolstogouzov, O. Teodoro, R. Zboril, R. Varma, AND P. Branco. Magnetically recyclable magnetite-palladium (Nanocat-Fe-Pd) nanocatalyst for the Buchwald-Hartwig reaction. GREEN CHEMISTRY. Royal Society of Chemistry, Cambridge, Uk, 16(7):3494-3500, (2014).

Impact/Purpose:

Submitted to Royal Society of Chemistry (RSC) journal, Green Chemistry

Description:

The immobilization of Pd on magnetite surface afforded (Nanocat-Fe-Pd) using inexpensive precursors and its catalytic role in the Buchwald-Hartwig reaction for arylation of amines and amides was investigated; C-N bond formation was achieved in moderate to excellent yields and the catalyst could be separated and recycled up to five cycles by magnetic decantation without significant loss in yield.

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