EPA Science Inventory

Magnetically recyclable magnetite-palladium (Nanocat-Fe-Pd) nanocatalyst for the Buchwald-Hartwig reaction

Citation:

Sa, S., M. Gawande, A. Velhinho, J. Veiga, N. Bundaleski, J. Triqueiro, A. Tolstogouzov, O. Teodoro, R. Zboril, R. Varma, AND P. Branco. Magnetically recyclable magnetite-palladium (Nanocat-Fe-Pd) nanocatalyst for the Buchwald-Hartwig reaction. GREEN CHEMISTRY. Royal Society of Chemistry, Cambridge, Uk, 16(7):3494-3500, (2014).

Description:

The immobilization of Pd on magnetite surface afforded (Nanocat-Fe-Pd) using inexpensive precursors and its catalytic role in the Buchwald-Hartwig reaction for arylation of amines and amides was investigated; C-N bond formation was achieved in moderate to excellent yields and the catalyst could be separated and recycled up to five cycles by magnetic decantation without significant loss in yield.

Purpose/Objective:

Submitted to Royal Society of Chemistry (RSC) journal, Green Chemistry

URLs/Downloads:

http://dx.doi.org/10.1039/C4GC00558A   Exit

Record Details:

Record Type: DOCUMENT (JOURNAL/PEER REVIEWED JOURNAL)
Start Date: 07/01/2014
Completion Date: 07/01/2014
Record Last Revised: 09/29/2015
Record Created: 06/30/2014
Record Released: 06/30/2014
OMB Category: Other
Record ID: 279783

Organization:

U.S. ENVIRONMENTAL PROTECTION AGENCY

OFFICE OF RESEARCH AND DEVELOPMENT

NATIONAL RISK MANAGEMENT RESEARCH LABORATORY

SUSTAINABLE TECHNOLOGY DIVISION

CLEAN PROCESSES BRANCH