EPA Science Inventory

Magnetically recyclable magnetite-palladium (Nanocat-Fe-Pd) nanocatalyst for the Buchwald-Hartwig reaction

Citation:

sa, S., M. Gawande, P. Branco, R. Zboril, O. Teodoro, AND R. Varma. Magnetically recyclable magnetite-palladium (Nanocat-Fe-Pd) nanocatalyst for the Buchwald-Hartwig reaction. GREEN CHEMISTRY. Royal Society of Chemistry, Cambridge, Uk, 16:3494-3500, (2014).

Description:

The immobilization of Pd on magnetite surface afforded (Nanocat-Fe-Pd) using inexpensive precursors and its catalytic role in the Buchwald-Hartwig reaction for arylation of amines and amides was investigated; C-N bond formation was achieved in moderate to excellent yields and the catalyst could be separated and recycled up to five cycles by magnetic decantation without significant loss in yield.

Purpose/Objective:

Submitted to Royal Society of Chemistry (RSC) journal, Green Chemistry

URLs/Downloads:

http://pubs.rsc.org/en/content/articlelanding/2014/gc/c4gc00558a#!divAbstract   Exit

Record Details:

Record Type: DOCUMENT (JOURNAL/PEER REVIEWED JOURNAL)
Completion Date: 06/30/2014
Record Last Revised: 06/30/2014
Record Created: 06/30/2014
Record Released: 06/30/2014
OMB Category: Other
Record ID: 279783

Organization:

U.S. ENVIRONMENTAL PROTECTION AGENCY

OFFICE OF RESEARCH AND DEVELOPMENT

NATIONAL RISK MANAGEMENT RESEARCH LABORATORY

SUSTAINABLE TECHNOLOGY DIVISION

CLEAN PROCESSES BRANCH