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AS SPECIATION AND EFFECTS OF PH AND PHOSPHATE ON THE MOBILIZATION OF AS IN SOILS FROM A LEAD SMELTING SITE. PUBLISHED IN ADVANCED PHOTON SOURCE ACTIVITY REPORT 2003.
Citation:
IMPELLITTERI, CHRISTOPHER. AS SPECIATION AND EFFECTS OF PH AND PHOSPHATE ON THE MOBILIZATION OF AS IN SOILS FROM A LEAD SMELTING SITE. PUBLISHED IN ADVANCED PHOTON SOURCE ACTIVITY REPORT 2003. Department of Energy, Office of Scientific and Technical Information, Oak Ridge, TN, EPA/600/R-07/088, 2004.
Impact/Purpose:
to inform the public
Description:
Arsenic in soils from the Asarco lead smelter in East Helena, Montana was characterized by X-ray absorption spectroscopy (XAS). Arsenic oxidation state and mineralogy were analyzed as a function of depth and surface distribution using bulk and microprobe XAS. These results were compared with data from macroscopic scale desorption/dissolution experiments. The experiments focused on the effects of phosphate and pH on the desorption/dissolution of As.