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HIGH PERMEABILITY MEMBRANES FOR THE DEHYDRATION OF LOW WATER CONTENT ETHANOL BY PERVAPORATION
Citation:
NAMBOODIRI, VASU V. AND L. M. VANE. HIGH PERMEABILITY MEMBRANES FOR THE DEHYDRATION OF LOW WATER CONTENT ETHANOL BY PERVAPORATION. doi:10.1016/j.memsci, W.J. Koros (ed.), JOURNAL OF MEMBRANE SCIENCE. Elsevier Science Ltd, New York, NY, 306(1-2):209-215, (2007).
Impact/Purpose:
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Description:
Energy efficient dehydration of low water content ethanol is a challenge for the sustainable production of fuel-grade ethanol. Pervaporative membrane dehydration using a recently developed hydrophilic polymer membrane formulation consisting of a cross-linked mixture of poly(allylamine hydrochloride) and a blend of 99 and 88% hydrolyzed poly(vinyl alcohol) is found to be an attractive method. These polymeric membranes possess high water permeabilities at low feed water concentrations (<5 wt%) in ethanol compared to similar membranes in which all of the poly(vinyl alcohol) portion was 99% hydrolyzed.