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VAPOR PRESSURES, LIQUID MOLAR VOLUMES, VAPOR NON- IDEALITIES, AND CRITICAL PROPERTIES OF SOME FLUORINATED ETHERS: CF3OCF2OCF3, CF3OCF2 CF2H, c-CF2CF2CF2O, CF3OCF2H, AND CF3OCH3; AND OF CCl3F AND CF2ClH
Citation:
Wang, B., J. L. Adcock, S. B. Mathur, AND W. A. Van Hook. VAPOR PRESSURES, LIQUID MOLAR VOLUMES, VAPOR NON- IDEALITIES, AND CRITICAL PROPERTIES OF SOME FLUORINATED ETHERS: CF3OCF2OCF3, CF3OCF2 CF2H, c-CF2CF2CF2O, CF3OCF2H, AND CF3OCH3; AND OF CCl3F AND CF2ClH . JOURNAL OF CHEMICAL THERMODYNAMICS 23(7):699-710, (1991).
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Information.
Description:
Vapor pressures, compressibilities, expansivities, and molar volumes of the liquid phase have been measured between room temperature and the critical temperature for a series of fluorinated ethers: CF3OCF2OCF3, CF3OCF2CF2H, c-CF2CF2CF2O, CF3OCF2H, and CF3OCH3. Vapor-phase non-idealities were measured for each compound, but only for samples of high vapor density. Critical temperatures and pressures and approximate melting and boiling temperatures are reported. Apparatus calibrations were checked with measurements on the well characterized materials: CFCl3, (R11) and CF2ClH (R22).
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VAPOR PRESSURES, LIQUID MOLAR VOLUMES, VAPOR NON- IDEALITIES, AND CRITICAL PROPERTIES OF SOME FLUORINATED ETHERS, ETC. (PDF, NA pp, 2448 KB, about PDF)