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RECORD NUMBER: 35 OF 35

Main Title Reaction kinetics of ozone with sulfur compounds /
Author Erickson, Ronald E.,; Yates., Leland M.
CORP Author Montana Univ., Missoula. Dept. of Chemistry.;Environmental Sciences Research Lab., Research Triangle Park, N.C. Gas Kinetics and Photochemistry Branch.
Publisher U.S. Environmental Protection Agency,
Place Published Research Triangle Park, N.C.
Year Published 1976
Report Number EPA-600/3-76-089; EPA-R-800655
Stock Number PB-257 891
OCLC Number 26142398
Subjects Ozone; Chemical reactions; Sulfur dioxide; Reaction kinetics; pH; Solutions(Chemistry); Organic sulfides; Air pollution; Chemical reaction mechanisms; Methyl sulfides; Methane thiols; Methyl disulfides
Subject Added Ent Air--Pollution.
Internet Access
Description Access URL
http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=20012TYT.txt
Holdings
Library   Call Number Additional Info Location Date Modified
EJAD EPA 600/3-76-089 Region 3 Library/Philadelphia, PA 06/16/2000
EJBD ARCHIVE EPA 600-3-76-089 Headquarters Library/Washington,DC 09/12/2011
EJBD EPA 600-3-76-089 c.1-2 Headquarters Library/Washington,DC 03/18/2014
EKAM EPA-600/3-76-089 Region 4 Library/Atlanta,GA 04/01/1994
EKBD EPA-600/3-76-089 Research Triangle Park Library/RTP, NC 07/11/2003
EOAD EPA 600/3-76-089 Region 8 Technical Library/Denver,CO 02/28/2011
ESAD EPA 600-3-76-089 Region 10 Library/Seattle,WA 03/23/2010
NTIS PB-257 891 Most EPA libraries have a fiche copy filed under the call number shown. Check with individual libraries about paper copy. NTIS 01/01/1988
Collation vii, 61 p. : charts ; 29 cm.
Abstract The report presents data on the reaction between ozone and several sulfur compounds which are air pollutants. The compounds of interest are sulfur dioxide, dimethyl sulfide, methanethiol and dimethyl disulfide. The rate of the reaction between ozone and dissolved sulfur dioxide is strongly pH dependent. This is so because sulfite ion reacts extremely rapidly (second order rate constant four orders of magnitude higher than that of bi-sulfite ion). These results suggest that under some conditions atmospheric oxidation of sulfur dioxide may involve ozone. Dimethyl sulfide was found to react extremely rapidly with ozone in the gas phase but reproducible kinetic data were not obtained. Stoichiometric and yield data from the reaction between ozone and methanethiol or dimethyl disulfide in aqueous solution indicate those reactions to be complex mechanistically, although one product, methane sulfonic acid is predominant.
Notes "Office of Research and Development." "EPA-600/3-76-089." "August 1976." Includes bibliographical references.
Author Added Ent
Yates, Leland M.;
Bufalini, Joseph J.
Corporate Au Added Ent United States. Environmental Protection Agency. Office of Research and Development.; University of Montana--Missoula.; Environmental Sciences Research Laboratory.
PUB Date Free Form 1976
NTIS Prices PC A04/MF A01
BIB Level m
OCLC Time Stamp 20110908100839
Cataloging Source OCLC/T
Language eng
Origin OCLC
Type MERGE
OCLC Rec Leader 01198cam 2200313Ka 45020


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