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Grantee Research Project Results

Publications Details for:

Federal Demonstration Partnership (FDP) solid-catalyzed reactions in supercritical reaction media
Grant Number R826034
RFA: Technology for a Sustainable Environment (1998)


Other views: Selected publication types Journal articles Publications submitted after final report Redisplay this page with Reference Title, Journal, and Author Columns Display this page in RIS format

Book Chapter (1)
Conference Proceedings (1)
Dissertation/Thesis (2)
Journal Article (6)
Patent/Patent Application (2)
Presentation (13)
Proceedings (1)
Reference Type Citation Progress Report Year Document Sources
Book Chapter Subramaniam B, Herkes FE, Arunajatesan V, Hutchenson KW. Continuous heterogeneous catalytic hydrogenation of organic compounds in supercritical CO2. In: Morrell DG, ed. Catalysis of Organic Reactions. Boca Raton, FL: CRC Press, 2002, Chapter 35, pp. 461-475.
abstract available    
R826034 (2001)
Conference Proceedings Subramaniam B, Arunajatesan V, Lyon CJ. Coking of solid acid catalysts and strategies for enhancing their activity. In: Delmon B, Froment GF, eds. Catalyst Deactivation 1999, Proceedings of the 8th International Symposium, Brugge, Belgium, 10-13 October, 1999, Studies in Surface Science and Catalysis Series Volume 126. Amsterdam, The Netherlands: Elsevier, 1999, pp. 63-77.
abstract available    
R824729 (Final)
R826034 (2000)
R826034 (2001)
Dissertation/Thesis Arunajatesan V. Enhancing multi-phase catalytic process efficiency with supercritical reaction media. Ph.D. Thesis. Department of Chemical and Petroleum Engineering, University of Kansas, July 2002.
R826034 (2001)
not available
Dissertation/Thesis Lyon CJ. Optimization of activity and selectivity by pressure-tuning during solid-acid catalyzed isoparaffin/olefin alkylation in supercritical carbon dioxide. Ph.D. Thesis. Department of Chemical and Petroleum Engineering, University of Kansas, June 2002.
R826034 (2001)
not available
Journal Article Arunajatesan V, Subramaniam B, Hutchenson KW, Herkes FE. Fixed-bed hydrogenation of organic compounds in supercritical carbon dioxide. Chemical Engineering Science 2001;56(4):1363-1369.
abstract available     full text available
R826034 (2000)
R826034 (2001)
Journal Article Arunajatesan V, Wilson KA, Subramaniam B. Pressure-tuning the effective diffusivity of near-critical reaction mixtures in mesoporous catalysts. Industrial & Engineering Chemistry Research 2003;42(12):2639-2643.
abstract available    
R826034 (2001)
Journal Article Clark MC, Subramaniam B. Kinetics on a supported catalyst at supercritical, nondeactivating conditions. AIChE Journal 1999;45(7):1559-1565.
abstract available     full text available
R824729 (Final)
R826034 (2001)
Journal Article Lyon CJ, Subramaniam B, Pereira CJ. Extended alkylate production on SiO2-supported Nafion at supercritical conditions.. Studies In Surface Sciences. 2001;139:221-228.
R826034 (2000)
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Journal Article Subramaniam B. Enhancing the stability of porous catalysts with supercritical reaction media. Applied Catalysis A: General 2001;212(1-2):199-213.
abstract available     full text available
R826034 (2000)
R826034 (2001)
Journal Article Subramaniam B, Lyon CJ, Arunajatesan V. Environmentally benign multiphase catalysis with dense phase carbon dioxide. Applied Catalysis B: Environmental 2002;37(4):279-292.
abstract available    
R826034 (2001)
Patent/Patent Application Subramaniam B, Saim S, Rajewski RA, Stella V. Methods for particle micronization and nanonization by recrystallization from organic solutions sprayed into a compressed antisolvent. U.S. Patent No. 5874029 A, February 23,1999.
abstract available     full text available
R824729 (Final)
R826034 (2001)
Patent/Patent Application Subramaniam B, Rajewski RA, Bochniak DJ. Process and apparatus for size selective separation of micro- and nano-particles. U.S. Patent No. 6113795 A, September 5, 2000.
abstract available     full text available
R824729 (Final)
R826034 (2001)
Presentation Subramaniam B. Coking of solid acid catalysts and their activity enhancement in supercritical reaction media. Presented at the 8th International Symposium on Catalyst Deactivation, Brugge, Belgium, October 10-13, 1999.
R826034 (2000)
R826034 (2001)
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Presentation Subramaniam B. Continuous solid-catalyzed reactions in supercritical reaction media: reaction engineering fundamentals and process scaleup considerations. Presented at the Fifth International Symposium on Supercritical Fluids, Atlanta, GA, April 8-12, 2000.
R826034 (2000)
R826034 (2001)
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Presentation Subramaniam B. Catalysis with supercritical reaction media: opportunities and challenges. Presented at Future Directions in Chemical Reaction Engineering Research, American Institute of Chemical Engineers (AIChE) Annual Meeting, Los Angeles, CA, November 12-17, 2000.
R826034 (2000)
R826034 (2001)
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Presentation Subramaniam B. Catalysis in dense CO2-based reaction media. Presented at the Green Catalysis Symposium, 37th Annual American Chemical Society Midwest Regional Meeting, Lawrence, KS, October 23-25, 2002.
R826034 (2001)
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Presentation Subramaniam B. Environmentally benign catalysis in dense CO2-based reaction media. Presented at the 4th International Symposium on High Pressure Process Technology and Chemical Engineering, Venice, Italy, September 22-25, 2002.
R826034 (2001)
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Presentation Subramaniam B. 1-butene/isobutane alkylation over unsupported and SiO2-supported Nafion in liquid and supercritical reaction phases. Presented at the American Institute of Chemical Engineers Annual Meeting, Los Angeles, CA, November 2000.
R826034 (2000)
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Presentation Subramaniam B. CO2-facilitated supercritical 1-butene/isobutane alkylation: comparison of solid acids with different acidities and pore structures. Presented at the American Institute of Chemical Engineers Annual Meeting, Dallas, TX, November 1999.
R826034 (2000)
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Presentation Subramaniam B. Catalysis and reaction engineering aspects of fixed-bed hydrogenation in supercritical carbon dioxide. Presented at the American Institute of Chemical Engineers Annual Meeting, Dallas, TX, November 1999.
R826034 (2000)
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Presentation Subramaniam B. Catalysis and reaction engineering aspects of fixed-bed hydrogenation in supercritical carbon dioxide. Presented at the Sixteenth International Symposium on Chemical Reaction Engineering, Poland, September 2000.
R826034 (2000)
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Presentation Subramaniam B. Catalysis in supercritical media. Presented at the First North American Symposium on Chemical Reaction Engineering, Houston, TX, January 2001.
R826034 (2000)
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Presentation Subramaniam B. Environmentally benign catalytic processing with near-critical carbon dioxide. Presented at the EPA/National Science Foundation Technology for a Sustainable Environment Initiative, American Institute of Chemical Engineers Annual Meeting, November 2000.
R826034 (2000)
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Presentation Subramaniam B. Exploiting near-critical reaction media in heterogeneous catalysis. Presented at the Third Green Chemistry and Engineering Conference, Washington, DC, June 1999.
R826034 (2000)
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Presentation Subramaniam B. Near-critical 1-butene/isobutane alkylation on solid acid catalysts facilitated by carbon dioxide. Presented at the American Chemical Society National Meeting, New Orleans, LA, August 1999.
R826034 (2000)
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Proceedings Lyon C, Subramaniam B, Pereira C. Enhanced isooctane yields for 1-butene/isobutane alkylation on SiO2-supported Nafion® in supercritical carbon dioxide. In: Spivey JJ, Roberts GW, Davis BH, eds. Catalyst Deactivation 2001: Proceedings of the 9th International Symposium, Lexington, KY, October 7-10 2001, Studies in Surface Science and Catalysis Series Volume 139. Amsterdam, The Netherlands: Elsevier, 2001, pp. 221-228.
abstract available    
R826034 (2001)

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The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Conclusions drawn by the principal investigators have not been reviewed by the Agency.

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