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Grantee Research Project Results

Grantee Research Project Results

Publications Details for:

Nearcritical Water as a Reaction Solvent
Grant Number R828130
RFA: Technology for a Sustainable Environment (1999)


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Journal Article (10)
Presentation (22)
Proceedings (1)
Reference Type Citation Progress Report Year Document Sources
Journal Article Brown JS, Glaser R, Liotta CL, Eckert CA. Acylation of activated aromatics without added acid catalyst. Chemical Communications 2000;14:1295-1296.
R828130 (Final)
not available
Journal Article Brown JS, Hallett JP, Bush D, Eckert CA. Liquid-liquid equilibria for binary mixtures of water plus acetophenone, plus 1-octanol, plus anisole, and plus toluene from 370 K to 550 K. Journal of Chemical and Engineering Data 2000;45(5):846-850
abstract available    
R828130 (Final)
not available
Journal Article Eckert CA, Liotta CL, Brown JS. Clean solution for chemical synthesis. Chemistry and Industry 2000;3:94-97.
R828130 (Final)
not available
Journal Article Eckert CA, Bush D, Brown JS, Liotta CL. Tuning solvents for sustainable technology. Industrial and Engineering Chemistry Research 2000;39(12):4615-4621.
R828130 (Final)
not available
Journal Article Jones JR, Liotta CL, Collard DM, Schiraldi DA. Photochemical cross-linking of poly(ethylene terephthalate-co-2,6-anthracenedicarboxylate). Macromolecules 2000;33(5):1640-1645
abstract available    
R828130 (Final)
not available
Journal Article Patrick HR, Griffith K, Liotta CL, Eckert CA, Glaser R. Near-critical water: A benign medium for catalytic reactions. Industrial & Engineering Chemistry Research 2001;40(26):6063-6067
abstract available    
R828130 (Final)
not available
Journal Article Lu J, Brown JS, Liotta CL, Eckert CA. Polarity and hydrogen-bonding of ambient to near-critical water: Kamlet-Taft solvent parameters. Chemical Communications 2001;(7):665-666
abstract available    
R828130 (Final)
not available
Journal Article Lu J, Boughner EC, Liotta CL, Eckert CA. Nearcritical and supercritical ethanol as a benign solvent: polarity and hydrogen-bonding. Fluid Phase Equilibria 2002;198(1):37-49.
abstract available    
R828130 (Final)
not available
Journal Article Lu J, Brown JS, Boughner EC, Liotta CL, Eckert CA. Solvatochromic characterization of near-critical water as a benign reaction medium. Industrial & Engineering Chemistry Research 2002;41(12):2835-2841
abstract available    
R828130 (Final)
not available
Journal Article Nolen SA, Liotta CL, Eckert CA, Glaser R. The catalytic opportunities of near-critical water: a benign medium for conventionally acid and base catalyzed condensations for organic synthesis. Green Chemistry 2003;5(5):663-669
R828130 (Final)
not available
Presentation Brown J, Hallett JP, Glaser R, Liotta CL. Catalysis with environmentally benign solvents at elevated temperature and pressure. Presented at the American Institute of Chemical Engineers Annual Meeting, Los Angeles, CA, November 2000.
R828130 (Final)
not available
Presentation Brown J, Glaser R, Eckert CA, Liotta CL. Environmentally benign chemical processing alternatives using acetic acid and nearcritical water. Presented at the Green Chemistry Meeting, Washington, DC, June 2000.
R828130 (Final)
not available
Presentation Eckert CA. Expanded solvents for sustainable technology. Presented at the Laboratoire de Thermodynamique des Equilibres entre Phases, Centre Reacteurs et Processus, Ecole Nationale Superieure des Mines de Paris, Fontainebleau, France, April 12, 2002.
R828130 (Final)
not available
Presentation Eckert CA. Expanded solvents for sustainable technology. Presented at the Chemical Engineering Department, University of Illinois, Chicago, IL, February 21, 2002.
R828130 (Final)
not available
Presentation Eckert CA. Expanded solvents for sustainable technology. Presented at the Chemical Engineering Department, University of Kansas, Lawrence, KS, October 23, 2001.
R828130 (Final)
not available
Presentation Eckert CA, Liotta CL. Nontraditional solvents for sustainable chemical processes. Presented at the Midwest American Chemical Society Meeting, Lawrence, KS, October 24, 2002.
R828130 (Final)
not available
Presentation Eckert CA, Bush D, Lazzaroni MJ. Solvent selection for separations and reactions. Presented to the Dow Chemical Company, Midland, MI, October 9, 2002.
R828130 (Final)
not available
Presentation Eckert CA, Glaser R, Brown JS. Tuning of chemical reactions with expanded solvents. Presented at the 5th Conference on Supercritical Fluids and Their Applications, Associanzione Italiana di Ingregneria Chimica, Verona, Italy, June 1999.
R828130 (Final)
not available
Presentation Glaser R, Brown JS, Liotta CL, Eckert CA. Base-catalyzed reactions in near-critical water for environmentally benign chemical processing. Presented at the 217th American Chemical Society National Meeting, Anaheim, CA, March 1999.
R828130 (Final)
not available
Presentation Hallett J, Bush D, Eckert CA, Brown J. High temperature water/organic liquid-liquid equilibria. Presented at the American Institute of Chemical Engineers Annual Meeting, Los Angeles, CA, November 2000.
R828130 (Final)
not available
Presentation Hallett J, Bush D, Eckert CA, Brown J. Organic/water phase equilibria at high temperature. Presented at the National Institute of Standards and Technology, Boulder, CO, June 2000.
R828130 (Final)
not available
Presentation Lesutis HP, Glaser R, Eckert CA, Liotta CL. Acid- vs base-catalyzed ester hydrolysis in nearcritical water. Presented at the American Institute of Chemical Engineers Annual Meeting, Dallas, TX, November 2, 1999.
R828130 (Final)
not available
Presentation Lesutis HP, Glaser R, Griffith KN, Eckert CA, Liotta CL. Nearcritical water: a benign medium for catalytic reactions. Presented at the 5th International Symposium on Supercritical Fluids, Atlanta, GA, April 2000.
R828130 (Final)
not available
Presentation Lesutis HP, Glaser R, Griffith K, Eckert CA, Liotta CL. Self-neutralizing catalysis in nearcritical water. Presented at the Green Chemistry Meeting, Washington, DC, June 2000.
R828130 (Final)
not available
Presentation Liotta CL, Brown JS, West KN, Hallett JP, McCarnery JP, Nolen SA, Culp CW, Griffith K, Eckert CA, Glaser R. Green replacement solvents: environmentally benign solvent systems for chemical reactions and processes. Presented at the Southeast/Southwest Regional American Chemical Society Meeting, New Orleans, LA, December 5, 2000.
R828130 (Final)
not available
Presentation Lu J, Hallett J, Eckert CA, Bush D. Nearcritical water as a process solvent. Presented at the 16th International Union of Pure and Applied Chemistry Conference on Chemical Thermodyamics, Halifax, Nova Scotia, Canada, August 2000.
R828130 (Final)
not available
Presentation Lu J, Brown JS, Nolen SA, Hallett JP, Eckert CA, Liotta CL. Nearcritical water as a reaction medium. Presented at the 10th International Symposium on Supercritical Fluid Chromatography, Extraction, and Processing, Myrtle Beach, SC, August 23, 2001.
R828130 (Final)
not available
Presentation Lu J, Brown JS, Eckert CA, Liotta CL. Neutral acid-catalytic reactions in nearcritical water. Presented at the 5th Annual Green Chemistry and Engineering Conference, Washington, DC, June 26-28, 2001.
R828130 (Final)
not available
Presentation Lu J, Brown JS, Eckert CA, Liotta CL. Phase equilibria for near-critical water. Presented at the American Institute of Chemical Engineers Annual Meeting, Dallas, TX, November 2, 1999.
R828130 (Final)
not available
Presentation Lu J, Brown JS, West KN, Eckert CA, Liotta CL. Solvatochromic parameters for nearcritical water. Presented at the National Institute of Standards and Technology, Boulder, CO, June 2000.
R828130 (Final)
not available
Presentation Lu J, Brown JS, Bush D, Eckert CA, Liotta CL. Solvent effects on chemical reactions in nearcritical water. Presented at the American Institute of Chemical Engineers Annual Meeting, Los Angeles, CA, November 2000.
R828130 (Final)
not available
Presentation Lu J, Eckert CA, Liotta CL. Solvatochromic properties of near- and supercritical ethanol and nearcritical acetic acid. Presented at the American Institute of Chemical Engineers Annual Meeting, Los Angeles, CA, November 2000.
R828130 (Final)
not available
Proceedings Glaser R, Brown JS, Liotta CL, Eckert CA. Base-catalyzed reactions in near-critical water for environmentally benign chemical processing. In: Proceedings of the 217th American Chemical Society National Meeting Symposium Preprint, Chemistry of Renewable Fuels and Chemicals, Anaheim, CA, March 1999, Vol. 44, No. 2, pp. 385-388.
R825325 (Final)
R828130 (Final)
not available

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The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Conclusions drawn by the principal investigators have not been reviewed by the Agency.

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