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Grantee Research Project Results

Grantee Research Project Results

Publications Details for:

Towards Elimination of Transition Metals and VOCs from the Environmentally Benign Materials Made by Atom Transfer Radical Polymerization (ATRP)
Grant Number R829580
RFA: Technology for a Sustainable Environment (2001)


Other views: Selected publication types Journal articles Publications submitted after final report Redisplay this page with Reference Title, Journal, and Author Columns Display this page in RIS format

Abstract (8)
Book (2)
Book Chapter (3)
Journal Article (18)
Patent/Patent Application (11)
Reference Type Citation Progress Report Year Document Sources
Abstract Hong SC, Matyjaszewski K. An immobilized/soluble hybrid catalyst systems for atom transfer radical polymerization. Abstracts of Papers of the American Chemical Society 2002;224(POLY Pt 2):U439.
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Abstract Ke M, Li M, Jahed NM, Matyjaszewski K. Synthesis of star block copolymers via SR&NI ATRP in miniemulsion. American Chemical Society Polymer Preprints 2004;45(2):682-683.
abstract available    
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Abstract Lutz J-F, Matyjaszewski K. 600 MHz 1h NMR study of chain-end functionality in atom transfer radical polymerization. American Chemical Society Polymer Preprints 2002;43:229-230.
abstract available    
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Abstract Lutz JF, Matyjaszewski K. Synthesis of graft terpolymers poly(alkyl methacrylate)-g-poly(D-lactic acid)/poly(dimethyl siloxane) using the grafting through method in atom transfer radical polymerization. American Chemical Society Polymer Preprints 2002;43:231-232.
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Abstract Sarbu T, Matyjaszewski K. Iron and copper mediated ATRP of methyl methacrylate in the presence of ionic liquids. American Chemical Society Polymer Preprints 2002;43(2):211-212.
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Abstract Tsarevsky NV, Matyjaszewski K. Rational design of the catalyst for atom transfer radical polymerization in aqueous media. American Chemical Society Polymer Preprints 2004;45(2):89-90.
abstract available    
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Abstract Tsarevsky NV, Matyjaszewski K. Synthesis of well-defined (co)polymers with ionic or ionizable groups by atom transfer radical polymerization in aqueous media. American Chemical Society Polymer Preprints 2004;45(2):288-289.
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Abstract Tsarevsky NV, Matyjaszewski K. Synthesis of well-defined (bio)degradable polymeric materials with disulfide bonds by atom transfer radical polymerization. American Chemical Society Polymer Preprints 2005;46(1):339-340.
R829580 (Final)
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Book Davis KA, Matyjaszewski K. Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations, Advances In Polymer Science Series, Volume 159. New York, NY: Springer, 2002, 192 pp.
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Book Davis KA, Matyjaszewski K. Statistical, Gradient, Block, and Graft Copolymers by Controlled/Living Radical Polymerizations, Advances in Polymer Science Series Volume 159. New York, NY: Springer, 2002, 192 pp.
abstract available    
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Book Chapter Gaynor S, Qiu J, Matyjaszewski K. Using atom transfer radical polymerization (ATRP) in environmentally benign processes. In:Lankey RL, Anastas PT, eds. Advancing Sustainability Through Green Chemistry and Engineering, American Chemistry Society (ACS) Symposium Series Volume 823. Washington, DC: American Chemical Society, 2002, Chapter 9, pp. 113-126.
abstract available    
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Book Chapter Matyjaszewski K. Comparison and classification of controlled/living radical polymerizations. In: Matyjaszewski K, ed. Controlled/Living Radical Polymerization: Progress in ATRP, NMP, and RAFT, American Chemical Society (ACS) Symposium Series Volume768. Washington, DC: American Chemical Society, 2000, Chapter 1, pp. 2-26.
abstract available     full text available
R826735 (2000)
R826735 (Final)
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Book Chapter Matyjaszewski K. New catalysts for controlled/living atom transfer radical polymerization (ATRP). In: Anpo M, Onaka M, Yamashita H, eds. Science and Technology in Catalysis 2002: Proceedings of the Fourth Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, July 14-19, 2002, Studies in Surface Science and Catalysis Series Volume 145. Amsterdam, The Netherlands: Elsevier, 2003, pp. 3-11.
abstract available    
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Journal Article Davis KA, Matyjaszewski K. Effect of (pseudo)halide initiators and copper complexes with non-halogen anions on the atom transfer radical polymerization. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry 2004;41(5):449-465.
abstract available    
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Journal Article Gromada J, Spanswick J, Matyjaszewski K. Synthesis and ATRP activity of new TREN-based ligands. Macromolecular Chemistry and Physics 2004;205(5):551-566.
abstract available    
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Journal Article Hong SC, Lutz J-F, Inoue Y, Strissel C, Nuyken O, Matyjaszewski K. Use of an immobilized/soluble hybrid ATRP catalyst system for the preparation of block copolymers, random copolymers, and polymers with high degree of chain end functionality. Macromolecules 2003;36(4):1075-1082.
abstract available     full text available
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Journal Article Hong SC, Neugebauer D, Inoue Y, Lutz J-F, Matyjaszewski K. Preparation of segmented copolymers in the presence of an immobilized/soluble hybrid ATRP catalyst system. Macromolecules 2003;36(1):27-35.
abstract available     full text available
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Journal Article Lee SB, Russell AJ, Matyjaszewski K. ATRP synthesis of amphiphilic random, gradient, and block copolymers of 2-(dimethylamino)ethyl methacrylate and n-butyl methacrylate in aqueous media. Biomacromolecules 2003;4(5):1386-1393.
abstract available     full text available
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Journal Article Li M, Matyjaszewski K. Reverse atom transfer radical polymerization in miniemulsion. Macromolecules 2003;36(16):6028-6035.
abstract available     full text available
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Journal Article Li M, Jahed NM, Min K, Matyjaszewski K. Preparation of linear and star-shaped block copolymers by ATRP using simultaneous reverse and normal initiation process in bulk and miniemulsion. Macromolecules 2004;37(7):2434-2441.
abstract available     full text available
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Journal Article Lutz J-F, Matyjaszewski K. Kinetic modeling of the chain-end functionality in atom transfer radical polymerization. Macromolecular Chemistry and Physics 2002;203(10-11):1385-1395.
abstract available    
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Journal Article Lutz J-F, Jahed N, Matyjaszewski K. Preparation and characterization of graft terpolymers with controlled molecular structure. Journal of Polymer Science, Part A: Polymer Chemistry 2004;42(8):1939-1952.
abstract available    
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Journal Article Lutz J-F, Matyjaszewski K. Nuclear magnetic resonance monitoring of chain-end functionality in the atom transfer radical polymerization of styrene. Journal of Polymer Science, Part A: Polymer Chemistry 2005;43(4):897-910.
abstract available    
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Journal Article Matyjaszewski K. From atom transfer radical addition to atom transfer radical polymerization. Current Organic Chemistry 2002;6(2):67-82.
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Journal Article Matyjaszewski K, Spanswick J. Controlled/living radical polymerization. Materials Today 2005;8(3):26-33.
abstract available     full text available
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Journal Article Li M, Min K, Matyjaszewski K. ATRP in waterborne miniemulsion via a simultaneous reverse and normal initiation process. Macromolecules 2004;37(6):2106-2112.
abstract available     full text available
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Journal Article Sarbu T, Pintauer T, McKenzie B, Matyjaszewski K. Atom transfer radical polymerization of styrene in toluene/water mixtures. Journal of Polymer Science, Part A: Polymer Chemistry 2002;40(18):3153-3160.
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Journal Article Sarbu T, Lin K-Y, Spanswick J, Gil RR, Siegwart DJ, Matyjaszewski K. Synthesis of hydroxy-telechelic poly(methyl acrylate) and polystyrene by atom transfer radical coupling. Macromolecules 2004;37(26):9694-9700.
abstract available     full text available
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Journal Article Sun F, Sheiko SS, Moller M, Beers K, Matyjaszewski K. Conformational switching of molecular brushes in response to the energy of interaction with the substrate. Journal of Physical Chemistry A 2004;108(45):9682-9686.
abstract available     full text available
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Journal Article Tsarevsky NV, Pintauer T, Matyjaszewski K. Deactivation efficiency and degree of control over polymerization in ATRP in protic solvents. Macromolecules 2004;37(26):9768-9778.
abstract available     full text available
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Journal Article Tsarevsky NV, Matyjaszewski K. Combining atom transfer radical polymerization and disulfide/thiol redox chemistry: a route to well-defined (bio)degradable polymeric materials. Macromolecules 2005;38(8):3087-3092.
abstract available     full text available
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Patent/Patent Application Li M, Zhong Q, Raghunathan S. Nano-talc with hydrophobic coating. U.S. Patent No. 7,758,689, July 20, 2010.
abstract available    
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Patent/Patent Application Matyjaszewski K, Gaynor SG, Coca S. Atom or group transfer radical polymerization. U.S. Patent No. 6,541,580, April 1, 2003.
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Patent/Patent Application Matyjaszewski K, Gaynor SG, Coca S. Atom or group transfer radical polymerization. U.S. Patent No. 6,512,060, January 28, 2003.
abstract available    
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Patent/Patent Application Matyjaszewski K, Gaynor SG, Coca S. Atom or group transfer radical polymerization. U.S. Patent No. 6,538,091, March 25, 2003.
abstract available    
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Patent/Patent Application Matyjaszewski K, Wang JS. (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization. U.S. Patent No. 6,624,263, September 23, 2003.
abstract available    
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Patent/Patent Application Matyjaszewski K, Tsarevsky N. Polymerization process for ionic monomers. U.S. Patent No. 6,624,262, September 23, 2003.
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Patent/Patent Application Matyjaszewski K, Pyun J. The preparation of nanocomposite structures by controlled radical polymerization processes. U.S. Patent 6,627,314, September 30, 2003.
abstract available    
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Patent/Patent Application Matyjaszewski K, Gromada J, Li M. Simultaneous reverse and normal initiation of ATRP. U.S. Patent No. 6,759,491, July 6 2004.
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Patent/Patent Application Matyjaszewski K, Kowalewski T, Lambeth DN, Spanswick J, Tsarevsky NV. Process for the preparation of nanostructured materials. U.S. Patent No. 7,056,455, June 6, 2006.
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Patent/Patent Application Matyjaszewski K, Pakula T. Polymers, supersoft elastomers and methods for preparing the same. U.S. Patent No. 7,019,082, March 28, 2006.
abstract available    
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Patent/Patent Application Matyjaszewski K, Tsarevsky NV. Stabilization of transition metal complexes for catalysis in diverse environments. U.S. Patent No. 7,332,550, February 19, 2008.
abstract available    
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The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Conclusions drawn by the principal investigators have not been reviewed by the Agency.

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