Jump to main content
US EPA
United States Environmental Protection Agency
Search
Search
Main menu
Environmental Topics
Laws & Regulations
About EPA
Health & Environmental Research Online (HERO)
Contact Us
Print
Feedback
Export to File
Search:
This record has one attached file:
Add More Files
Attach File(s):
Display Name for File*:
Save
Citation
Tags
HERO ID
625722
Reference Type
Journal Article
Title
Occupational exposure to aromatic hydrocarbons at a coke plant: Part II. Exposure assessment of volatile organic compounds
Author(s)
Bieniek, G; Kurkiewicz, S; Wilczok, T; Klimek, K; Swiatkowska, L; Lusiak, A
Year
2004
Is Peer Reviewed?
Yes
Journal
Journal of Occupational Health
ISSN:
1341-9145
EISSN:
1348-9585
Volume
46
Issue
3
Page Numbers
181-186
Language
English
PMID
15215658
DOI
10.1539/joh.46.181
Web of Science Id
WOS:000221983100002
URL
https://www.scopus.com/inward/record.uri?eid=2-s2.0-3042694503&doi=10.1539%2fjoh.46.181&partnerID=40&md5=5feb407eae732264898b120970a48971
Exit
Abstract
The objective of the study is to assess the external and internal exposures to aromatic hydrocarbons in the tar and oil naphthalene distillation processes at a coke plant. 69 workers engaged as operators in tar and oil naphthalene distillation processes and 25 non-exposed subjects were examined. Personal analyses of the benzene, toluene, xylene isomers, ethylbenzene, naphthalene, indan, indene and acenaphthene in the breathing zone air allowed us to determine the time weighted average exposure levels to the aromatic hydrocarbons listed above. The internal exposure was investigated by measurement of the urinary excretion of naphthols, 2-methylphenol and dimethylphenol isomers by means of gas chromatography with a flame ionization detection (GC/FID). Urine metabolites were extracted after enzymatic hydrolysis by solid-phase extraction with styrene-divinylbenzene resin. The time-weighted average concentrations of the hydrocarbons detected in the breathing zone air shows that the exposure levels of the workers are relatively low in comparison to the exposure limits. Statistically significant differences between average concentrations of aromatic hydrocarbons (benzene, toluene, xylene isomers) determined at the workplaces in the tar distillation department have been found. Concentrations of the naphthalene and acenaphthene detected in workers from the oil distillation department are higher that those from the tar distillation department. Concentrations of naphthols, 2-methoxyphenol and dimethylphenol isomers in the urine of occupationally exposed workers were significantly higher than those of non-exposed subjects. Concentrations of the 2-methoxyphenol and dimethylphenol isomers in urine were significantly higher for the tar distillation workers, whereas concentrations of naphthols were higher for the oil naphthalene distillation workers. Operators at the tar and naphthalene oil distillation processes are simultaneously exposed to a mixture of different hydrocarbons, mainly benzene and naphthalene homologues.
Keywords
mixed exposure; urinary metabolites; GC/FID analysis
Tags
•
Ethylbenzene
Database searches
WOS
LitSearch Update 2019
WOS
New Litsearch 4/2019
PubMed
Pre-2020 Screening HERO tags
Data set for title/abstract screening
Excluded – PECO criteria not met
•
Naphthalene
Previous HERO references
Database Searches
PubMed
WOS
Combined data set
Data set for title/abstract screening
Excluded - PECO criteria not met (TIAB)
Other
•
Naphthalene (2021 Evidence mapping publication)
Previous HERO references
Database Searches
PubMed
WOS
Combined data set
Data set for title/abstract screening
Excluded – PECO criteria not met
Home
Learn about HERO
Using HERO
Search HERO
Projects in HERO
Risk Assessment
Transparency & Integrity